1 / 18

Redox Neutral Reactions

Redox Neutral Reactions. Wang Chao 2011.3.12. Redox Economy and Redox Neutral Reactions:. Angew. Chem. Int. Ed. 2009, 48, 2854 – 2867. Developed by Noyori; Employed by Takasago in total synthesis of Menthol. Scheidt: J. AM. CHEM. SOC. 2009, 131 , 18028–18029. Hydride Shift Reactions:

darby
Télécharger la présentation

Redox Neutral Reactions

An Image/Link below is provided (as is) to download presentation Download Policy: Content on the Website is provided to you AS IS for your information and personal use and may not be sold / licensed / shared on other websites without getting consent from its author. Content is provided to you AS IS for your information and personal use only. Download presentation by click this link. While downloading, if for some reason you are not able to download a presentation, the publisher may have deleted the file from their server. During download, if you can't get a presentation, the file might be deleted by the publisher.

E N D

Presentation Transcript

  1. Redox Neutral Reactions Wang Chao 2011.3.12

  2. Redox Economy and Redox Neutral Reactions: Angew. Chem. Int. Ed. 2009, 48, 2854 – 2867

  3. Developed by Noyori; Employed by Takasago in total synthesis of Menthol

  4. Scheidt: J. AM. CHEM. SOC. 2009, 131, 18028–18029

  5. Hydride Shift Reactions: transition metals, lewis acids, organocatalysis recent examples: Akiyama:J. Am. Chem. Soc. 2011, 133, 2424–2426 Seidel:J. Am. Chem. Soc. 2011, 133, 2100–2103

  6. Borrowing Hydrogen: reduction and oxidation coupled Adv. Synth. Catal. 2007, 349, 1555 – 1575

  7. Breit: J. Am. Chem. Soc. 2011, 133, 2386–2389

  8. Transition metal mediated dehydrogenative activation Chem. Rev. 2010, 110, 681–703

  9. N-Alkylation of Amines by Alcohols: Alkylation of Activated Nucleophiles by Alcohols:

  10. Transfer Hydrogenative C-C Coupling: Krische: Angew. Chem. Int. Ed. 2009, 48, 34–46 J. Am. Chem. Soc. 2007, 129, 15134. Angew. Chem., Int. Ed. 2008, 47, 5220. J. Am. Chem. Soc. 2008, 130, 14891.

  11. Hydroacylation:

  12. Mechanism of activation of alcohol:

More Related