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Figures S7a and S7b

243.8. 100. 172.9. 90. 80. 70. 60. Relative Abundance. 50. 40. 30. 367.9. 20. 156.0. 10. 213.8. 0. 120. 140. 160. 180. 200. 220. 240. 260. 280. 300. 320. 340. 360. 380. 400. m/z. 324.9. 100. 90. 80. 70. 60. Relative Abundance. 50. 40. 30. 20. 201.0. 10.

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Figures S7a and S7b

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  1. 243.8 100 172.9 90 80 70 60 Relative Abundance 50 40 30 367.9 20 156.0 10 213.8 0 120 140 160 180 200 220 240 260 280 300 320 340 360 380 400 m/z 324.9 100 90 80 70 60 Relative Abundance 50 40 30 20 201.0 10 0 120 140 160 180 200 220 240 260 280 300 320 340 360 380 400 420 m/z a AAA(Aze)A y3+ y2+ -H2O y2+-NH3 b3+ b4+ b AAA(Pip)A y2+ Figures S7a and S7b

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