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Autoclaving for PCB’s

Autoclaving for PCB’s. Status & POPs application. Well proven and available for many years. In general for PCBs (only the oil and transformer components such as ceramics, cardboard and wood are incinerated).

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Autoclaving for PCB’s

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  1. Autoclaving for PCB’s

  2. Status & POPs application • Well proven and available for many years. In general for PCBs (only the oil and transformer components such as ceramics, cardboard and wood are incinerated). • After decontamination, the various metals such as copper, steel and aluminium are sent to the metals recycling industry. • POPs application: PCB’s only - not for other POPs

  3. Technology description History: 3-6 times rinsing of units were not able to bring PCB’s down to 50mg/kg. No adequate decontamination of transformer internal components: 0.5% to 4% (conc) PCBs remained at core and windings after 18 hours of soaking and rinsing  Autoclaving solution Principle: Solvent decontamination process that extracts PCBs from contaminated material. Process: Extraction solvent disrobes and solubilises PCBs from casing wall surfaces and internal cores, coils and windings. The efficiency of decontamination is a function of induced cycles of phase changes of the extraction solvent within the material containing the PCBs.

  4. Recycling materials Transformers and capacitors reception in the plant PCB Transformers and capacitors decontamination Vacuum pumping (PCB) PCB liquids Thermic treatment (static furnace) Disassembling of tank and core Chloride recycling by HCL production Preparation of « large basket » Perchloroethylen distillation recycling Decontamination in autoclaves Complete Dismantling Finishing treatment in the copper kiln

  5. Technology description

  6. PART I: Adaptation Technology – Country A. Performance 1. Minimum pre-treatment: • Draining of contaminated oil from the materials. • Dismantling for transformers. • Sawing for capacitors. • Core, casing, ceramics and piping materials separation.

  7. PART I: Adaptation Technology - Country A. Performance (cont’d) 2. Destruction Efficiency (DE): • DE values of greater than 99,999% have been reported for all chlorinated compounds. • Input values: >10 000 mg/kg PCBs askarel transformers <10 000 mg/kg PCB’s mineral oil transformers

  8. PART I: Adaptation Technology - Country A. Performance (cont’d) 3. Toxic by-products:Vacuum pump air exhaust is treated by active carbon filters. No toxic by-products 4. Uncontrolled releases: --- 5. Capacity to treat all POPs:No, only PCB’s 6. Throughput:  quantity [tons/day, l/day] • Reach 50 t / day on cores • 12000 t/y (example) (incl PCB and metal) • POPs throughput : [POPs waste/total waste in %]

  9. PART I: Adaptation Technology - Country A. Performance (cont’d) 7. Wastes/residuals: Secondary waste stream volumes: --- Off gas treatment: The off gas is treated via an activated carbon filter. Flow of gas 125 nm3 / h - conforms with the EU norms of emission

  10. PART II: Adaption Country – Technology A.Resource needs: Example 9 X France • Power requirements: 1000 kVA • Water requirements: Closed – loop circuit. Volume flow is about 100 m3 / h (directly rejected after use). No real water consumption, but if no well available, cold water unit needed. • Reagents volumes:PCE as solvent. Amount needed ca 40 m3 Recycled and reused. Overall consumption PCE: 200 t/y • Weather tight buildings: • Hazardous waste personnel requirement: • Sampling requirements/facilities: • Peer sampling: • Laboratory requirements: • Communication systems: • Number of (un/skilled) personnel required:16 2 shifts of 8 personsComplex plant requires expertise to run

  11. PART II: Adaption Country – Technology B: Costs (for case related in % of total): • Argentina case taken: Total costs ca 1 Mio US $. Treatment cost between 3 and 5 USD/kg • Installation + commissioning: 5 % • Site preparation: 2 % • Energy & Telecom installation: 330 kVA • Monitoring: 1% • Compliance: • Reporting: 1% • Run without waste: • Run with waste: 0,3 to 0,5 USD/kg  • Decommissioning: 2 % • Landfilling: only for ceramics depending of local costs • Transport residues:

  12. PART II: Adaption Country – Technology C. Impact & D. Risks: • Discharges to air: 125 Nm3 / h of gas, treated according to the EU norms. • Discharges to water: none • Discharges to land: Ceramics: 400 t / y of non-contaminated neutral material are landfilled • Risks reagents applied: PCEwear tracing equipmt exposition • Risks of technology: limited Fire, but extensive fire fighting and prevention equipment installed, strict temp.controls • Operational risks:Mechanical risks due to manipulation of heavy metallic parts

  13. PART II: Adaption Country Technology E. Constructability & F. Output • Ease of installation & construction of plant: complex • Ease of shipping/transit: • Ease of operation: Complex plant requiring expertise to run in origin country • Ease of processing: complex • Generated waste (% of input waste):  • Deposited waste at landfill (% of input waste): • Waste quality properties (pH, TCLP):

  14. Autoclave Mexico

  15. Taiwan autoclaving

  16. Argentina Autoclaving

  17. Introduction of internal cores in autoclave

  18. Introduction materials in autoclave

  19. Taiwan Dismantling area

  20. Dismantling operation draining at metallic platform

  21. Dismantled materials

  22. Distillation column for Perchloroethylen recycling (France)

  23. Mobile autoclave Canada

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