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[ Ru (H)(H 2 )(PPh 2 CH 2 CH 2 PPh 2 ) 2 ] +

[ Ru (H)(H 2 )(PPh 2 CH 2 CH 2 PPh 2 ) 2 ] +. Albinati , A. et al., Inorg .  Chim .  Acta 259 , 1997 , 351-357. Inelastic Incoherent Neutron Scattering Proton Tunneling Spectrum. Rotational tunneling barrier 1.0 – 1.4 kcal/mol. Fe(H) 2 (H 2 )(PEtPh 2 ) 3.

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[ Ru (H)(H 2 )(PPh 2 CH 2 CH 2 PPh 2 ) 2 ] +

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  1. [Ru(H)(H2)(PPh2CH2CH2PPh2)2]+ Albinati, A. et al., Inorg. Chim. Acta259, 1997, 351-357

  2. Inelastic Incoherent Neutron ScatteringProtonTunneling Spectrum Rotational tunneling barrier 1.0 – 1.4 kcal/mol

  3. Fe(H)2(H2)(PEtPh2)3 Van derSluys, L. S., et al., J. Am. Chem. Soc.1990, 112, 4831-4841.

  4. IPNS at Argonne National Laboratory

  5. Hydrogen Bonding in Tetraacetylethane (TAE) resonance assisted hydrogen bonding model disordered keto-enoltautomers 20 K neutron diffraction study Piccoli, P. M. B. et al., J. Phys. Chem. A2008, 112, 6667-6677.

  6. 298 K difference Fourier map with H1 omitted from the structure factor calculation Temperature Dependence of H-Bonding Parameters 40 K 70 K 110 K 298 K

  7. Charge Density Distribution at 20 K – Results of Multipole Refinement Negative of the LaPlacian Model Deformation Density Positive density buildup in red shows where bonding and lone-pair electron density resides in the structure. A localized structure is observed at 20 K. Positive density buildup in red indicates shared electronic interactions.

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