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Periodic Trends

Periodic Trends. Periodic Trends. Periodic Trends are trends that occur across the periodic table and down the periodic table. Atomic Radius. Atomic Radius – size of the atom. . Decreases. Increases. . Atomic Radius. Radius decreases across a period

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Periodic Trends

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  1. Periodic Trends

  2. Periodic Trends • Periodic Trends are trends that occur across the periodic table and down the periodic table

  3. Atomic Radius • Atomic Radius – size of the atom  Decreases Increases 

  4. Atomic Radius • Radius decreases across a period • Increased effective nuclear charge due to decreased shielding • Radius increases down a group • Addition of principal quantum levels

  5. Ionization Energy • _________________– the energy required to remove one mole of electrons, from one mole of gaseous atoms, to produce one mole of ions  Increases Decreases 

  6. Ionization Energy • First ionization energy • Second Ionization energy • Ionization energies are measure in KJ/mol • The have positive values showing that energy must be put in to remove an electron

  7. Ionization Energy • The magnitude of the ionization energy depends on 2 things… • The nuclear charge (how many protons are present) • The shielding effect of the inner electrons

  8. Ionization Energy • Across • increase because the nuclear charge increasesand the electrons are being removed from the same principal quantum level (shell), experiencing no extra shielding, and are therefore held more strongly. • (You’re trying to remove a more & more negatives, but still have the same number of positives pulling in on the electrons. They are pulling harder because there are few negatives)

  9. Ionization Energy • Down • decrease because the outer electrons are further away from the nucleus • Therefore the electrons are held less strongly.

  10. Example • Consider the following ionization energies • What is the predicted charge of this atom?

  11. Electron affinity • _________________– the energy change when one mole of gaseous atoms gains one mole of electrons , to form one mole of gaseous atoms  Increases Decreases 

  12. Electron affinity • Affinity tends to increase across a period • Affinity tends to decrease as you go down in a period • Electrons farther from the nucleus • experience less nuclear attraction

  13. Eelctronegativity • _________________ - A measure of the ability of an atom in a chemical compound to attract electrons  Increases Decreases 

  14. Metallic Character • _________________ – how much like a metal the element is  Decreases Increases 

  15. Ionic Radius • which will be larger: • Cl or Cl-1

  16. Ionic Radius • which will be larger: • Na or Na+1

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