1 / 91

第六章 金属卡宾、卡拜

第六章 金属卡宾、卡拜. “ Fischer 型 ” 卡宾. (1) 中性卡宾 (neutral carbenes). (2) 阳离子卡宾 (Cationic Metal Carbenes).  6.2 金属卡拜. 1974 年， Mortreux 发现 Mo(CO) 6 和 PhOH 在十氢萘中能均相催化二取代炔烃的复分解反应， 但原料不能完全转化，与产物存在平衡. [Mo(CO) 3 (NH 3 ) 3 ] 和 [Mo(CO) 3 (MeCN) 3 ] 在没有苯酚的存在下、 辛烷中回流确实能催化该炔烃复分解反应的进行，因此他们

agalia
Télécharger la présentation

第六章 金属卡宾、卡拜

An Image/Link below is provided (as is) to download presentation Download Policy: Content on the Website is provided to you AS IS for your information and personal use and may not be sold / licensed / shared on other websites without getting consent from its author. Content is provided to you AS IS for your information and personal use only. Download presentation by click this link. While downloading, if for some reason you are not able to download a presentation, the publisher may have deleted the file from their server. During download, if you can't get a presentation, the file might be deleted by the publisher.

E N D

Presentation Transcript

  1. 第六章 金属卡宾、卡拜

  2. “Fischer型”卡宾

  3. (1) 中性卡宾(neutral carbenes)

  4. (2) 阳离子卡宾(Cationic Metal Carbenes)

More Related