Durham Technical Community College Hazard Communication Annual Training Requirement 2013 - 2014

1. Durham Technical Community CollegeHazard CommunicationAnnual Training Requirement 2013 - 2014 Your “Right to Know” Note: if a web-link does not seem to work, click it a second time.

2. Five Stages of the Program • (Material) Safety Data Sheets MSDSs and SDSs • Labeling and Marking Systems • Employee Training • Written Plan • Chemical Inventory List

3. Durham Technical Community CollegeHazard Communication (Material) Safety Data Sheets

4. Company Information Hazardous Ingredients Physical Data Fire and Explosion Data Health Hazard Data Reactivity Data Spill & Leak Procedures Special Protection Information Special Precautions Hazard Communication(Material) Safety Data Sheets Safety Data Sheets are replacing MSDSs after 2013.

5. (Material) Safety Data Sheets:Your Rights 1. Your employer must have an MSDS or SDS for every hazardous substance you use as part of your job. They are online at http://www.durhamtech.edu/faculty/safety/

6. Finding (M)SDS Information Online • Main DTCC web under QuickLinks: Emergency and Safety Information • Under DTCC Emergency Information: Chemical Safety Data • Directly: www.durhamtech.edu/faculty/safety/

7. MSDS & SDS onwww.durhamtech.edu/faculty/safety If you are in a Chemistry Lab, click the “Chemistry” link

8. Searching for (M)SDS Information • Type Ctrl-f for search-box (will appear on top or bottom of window) • Type part of the name or CAS# - the first ‘hit’ will be highlighted • Press the Enter-key to go to the next match • Click the link for (M)SDS

9. CLICK to View Actual Sheets Hazards: (M)SDS • SDS has the Hazards in Section 2. • MSDS has the Hazards in Section 3.

10. Every SDS Has These Sections • Section 1, Identification • Section 2, Hazard(s) • Section 3, Composition/ingredients • Section 4, First-aid & symptoms/effects • Section 5, Fire-fighting measures • Section 6, Accidental release measures • Section 7, Handling and storage • Section 8, Exposure controls & PPE.

11. Every SDS Has These Sections • Section 9, Physical and chemical properties • Section 10, Stability and reactivity. • Section 11, Toxicological information • Section 12, Ecological information • Section 13, Disposal considerations • Section 14, Transport information • Section 15, Regulatory information • Section 16, Other information

12. (Material) Safety Data Sheets:Your Rights 2. These MSDS or SDS must be available to you the entire time you are in the workplace. At DTCC (M)SDS sheets are available on-line and sometimes as a printed copy with the chemicals being used.

13. (Material) Safety Data Sheets:Your Rights If you request to see a copy of an MSDS/SDS for a product you use, and your supervisor cannot provide it after one working day, you may refuse to use that product or work in an area where it is being used. Note: Most (M)SDS are Online

14. (Material) Safety Data Sheets:Your Rights 4. If you request your own personal copy of an MSDS/SDS, your employer has 15 days to provide it. Ask your supervisor or the Safety Officer. Note: Online copies are printable

15. Durham Technical Community CollegeHazard Communication Labeling and Marking Systems

16. Labeling and Marking Systems • NFPA Diamonds • HMIS Labels • GHS Labels and Pictograms • Uniform Laboratory Hazard Signage System

17. Labeling and Marking SystemsNFPA Diamonds • Color coded, numerical rating system • Will be located near main entrances, fire alarm panels, or on outside entrance doors • Provide at-a-glance hazard information

18. Labeling and Marking SystemsNFPA Diamonds • Blue = Health • Red = Flammability • Yellow = Instability • White = Special hazard information

19. Labeling and Marking SystemsNFPA Diamonds • 4= Deadly Hazard • 3= Severe Hazard • 2= Moderate Hazard • 1= Slight Hazard • 0= No Hazard

20. Labeling and Marking SystemsHMIS Labels • Designed to go on individual containers of products that don’t have the manufacturer’s labels • Uses the same color code/numerical rating system as the NFPA diamonds 3 0 1 

21. Labeling Containers • You should never have any unattended, unlabeled hazardous chemical containers in your workplace! • Never use food containers for storage of hazardous chemicals! • Help with an unlabeled container: talk to your supervisor or the Safety Officer.

22. The Globally Harmonized System (GHS) for Hazard Classification and Labeling • Replaces our current system • Old labels gradually replaced • Old NFPA Diamonds on bottles replaced by Pictograms • Old NFPA 0-4 rating replaced by GHS category 5-1 • MSDSs replaced by SDSs

23. NFPA compared to GHS Ratings Old New NFPA GHS Category 1severe hazard Category 2serious hazard Category 3moderate hazard Category 4slight hazard Category 5minimal hazard 4 = severe 3 = serious 2 = Moderate 1 = Slight 0 = Minimal NOTE: 4 is severe in NFPA but corresponds to Category 1 in GHS Big numbers bad in NFPA but Little numbers are bad in GHS.

24. Pictograms Signify Hazards - Know These - Corrosive, Eye damage Aquatic toxicity Gases under pressure Oxidizers Explosives, Self-reactives ! Poison, Highly toxic, Fatal Systemic Effects: Carcinogen, Mutagen, Reproductive toxicity, Respiratory sensitizer, Target organ toxicity, Aspiration toxin Flammables, Pyrophoric,Organic peroxides Irritant, Skin sensitizer, Low toxicity, Narcotic effects

25. IDENTIFY The Circled Pictogram (2) (3) (5) (6) (7) (8) (9) ! Explosives, Self-reactive Gases under pressure Aquatic toxicity Corrosive Oxidizers Poison, Highly toxic Organ toxicity; Carcinogen Flammable Irritant; Skin sensitizer CLICK answer in box above Explosives, Self-reactives

26. IDENTIFY The Circled Pictogram (2) (3) (5) (6) (7) (8) (9) ! Explosives, Self-reactive Gases under pressure Aquatic toxicity Corrosive Oxidizers Poison, Highly toxic Organ toxicity; Carcinogen Flammable Irritant; Skin sensitizer CLICK answer in box above Flammable

27. IDENTIFY The Circled Pictogram (2) (3) (5) (6) (7) (8) (9) ! Explosives, Self-reactive Gases under pressure Aquatic toxicity Corrosive Oxidizers Poison, Highly toxic Organ toxicity; Carcinogen Flammable Irritant; Skin sensitizer CLICK answer in box above Pressurized Gasses

28. IDENTIFY The Circled Pictogram (2) (3) (5) (6) (7) (8) (9) ! Explosives, Self-reactive Gases under pressure Aquatic toxicity Corrosive Oxidizers Poison, Highly toxic Organ toxicity; Carcinogen Flammable Irritant; Skin sensitizer CLICK answer in box above Irritant

29. IDENTIFY The Circled Pictogram (2) (3) (5) (6) (7) (8) (9) ! Explosives, Self-reactive Gases under pressure Aquatic toxicity Corrosive Oxidizers Poison, Highly toxic Organ toxicity; Carcinogen Flammable Irritant; Skin sensitizer CLICK answer in box above Systemic or Organ toxic

30. IDENTIFY The Circled Pictogram (2) (3) (5) (6) (7) (8) (9) ! Explosives, Self-reactive Gases under pressure Aquatic toxicity Corrosive Oxidizers Poison, Highly toxic Organ toxicity; Carcinogen Flammable Irritant; Skin sensitizer CLICK answer in box above Corrosives

31. IDENTIFY The Circled Pictogram (2) (3) (5) (6) (7) (8) (9) ! Explosives, Self-reactive Gases under pressure Aquatic toxicity Corrosive Oxidizers Poison, Highly toxic Organ toxicity; Carcinogen Flammable Irritant; Skin sensitizer CLICK answer in box above Poisons

32. IDENTIFY The Circled Pictogram (2) (3) (5) (6) (7) (8) (9) ! Explosives, Self-reactive Gases under pressure Aquatic toxicity Corrosive Oxidizers Poison, Highly toxic Organ toxicity; Carcinogen Flammable Irritant; Skin sensitizer CLICK answer in box above Oxidizers

33. IDENTIFY The Circled Pictogram (2) (3) (5) (6) (7) (8) (9) ! Explosives, Self-reactive Gases under pressure Aquatic toxicity Corrosive Oxidizers Poison, Highly toxic Organ toxicity; Carcinogen Flammable Irritant; Skin sensitizer CLICK answer in box above Environmental or Aquatic Toxin

34. GHS labels use SIGNAL Words, HAZARD Statements and PICTOGRAMS • Signal Words • Hazard Statements • Pictograms (for hazard category 1 & 2) • Instructions The 2 Signal Words are: Warning or Danger

35. YouTube video on GHS labels Watch this video for more information on GHS Labels GHS HazCom Training Video Click this link

36. Labeling and Marking SystemsUniform Laboratory Signage • Located on laboratory and chemical storage area doors • Pictographs depict worst hazards present in lab or area

37. Labeling and Marking SystemsUniform Laboratory Signage • Always check with the appropriate personnel (lab manager, Safety Officer, etc.) before performing work or maintenance in a laboratory!

38. Durham Technical Community CollegeHazard Communication Employee Training

39. Hazard CommunicationEmployee Training • Training is required: • Within the first 30 days of employment • Whenever new hazards are introduced • Annually

40. Hazard CommunicationEmployee Training • The training must cover: • Requirements of regulations • Location and availability of (M)SDSs • Hazardous chemicals used in your workplace • Physical and health hazards • Measures for personal protection • Details and location of the written plan

41. Hazard CommunicationEmployee Training • Safety is 1stYOUR responsibility. • This presentation provides general safety “Right-To-Know” training. • Your Supervisor or Instructor is responsible for their employee or student’s specific safety orientation. • The DTCC Safety Officer may also be consulted with questions or concerns.

42. Personal Protective Equipment Examples • Eyewear (Safety Glasses, Goggles, Face-Shields) • Gloves (Hot-Cold, Electrical, Chemical) • Aprons, Lab Coats • Hearing Protection • Breathing (Respirators, Dust, Self-Contained BA) • Safety Shoes • Hard Hats

43. Durham Technical Community CollegeHazard Communication The Written Plan

44. Hazard CommunicationThe Written Plan You have a right to possess your own copy of DTCC’s written hazard communications plan available online at: http://www.durhamtech.edu/faculty/safety/HealthandSafetyManual.pdf Click this link for the printable document

45. Hazard CommunicationThe Written Plan If you are exposed to a hazardous substance at work, you should report it at once to your supervisor.

46. Hazard CommunicationChemical Inventory List Federal law requires an inventory of all chemicals on the DTCC campuses, and that it be updated annually. The Chemical Inventory List is available at: www.durhamtech.edu/faculty/safety Click this link for the page with the Excel inventory

47. Emergency Response If an emergency occurs in your area, have someone contact CAMPUS POLICE/SECURITY at x5555 or (919)536-7255 FIRE: Evacuate to outside locations posted on Evacuation Signage*. Use extinguisher if trained. SPILL: Evacuate area. Clean-up only if trained. EXPOSURE: rinse for 15 minutes with water. WEATHER: Move to Weather Shelter Rooms posted on Evacuation Signage*. SECURITY ISSUE: FLEE if safe - lock door and HIDE if not - FIGHT if necessary. *Posters are being installed in buildings now

48. Durham Technical Community CollegeHazard Communication BE SAFE, NOT SORRY! TO COMPLETE YOUR TRAININGGO TO THE NEXT SLIDE FOR A TEST OF YOUR KNOWLEDGE

49. TAKE THIS BRIEF TEST 10 Questions Use this button if you want to restart the test

50. Question 1: click the correct response 1. What is the purpose of an (M)SDS? It describes the hazards and properties of substances It protects you from illegal or hazardous form of the substance It contains all the information available about a substance It tests your knowledge about a chemical or substance.