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This article explores the chemistry of Bulk Molding Compounds (BMC) and their distinctive properties. BMCs are thermosetting materials that become permanently rigid when heated or cured, utilizing crosslinking mechanisms to enhance strength. We differentiate BMCs from thermoplastics, which can be remelted and reshaped. The article provides insights into resin choices, low-profile additives, fiberglass properties, and critical BMC metrics such as flexural strength, tensile strength, and thermal properties. Essential for engineers and material scientists developing advanced composite materials.
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Chemistry of BMC A World of Choices
What a BMC Is • Thermoset • Having the property of becoming • permanently hard and rigid when • heated or cured. Uses crosslinking as • the mechanism to develop rigidity and • strength.
What a BMC Isn’t • Thermoplastic • Having the property of softening or • fusing when heated and of hardening • and becoming rigid again when cooled; • thermoplastic materials can be • remelted and cooled time after time • without undergoing any appreciable • chemical change.
Resin Choices • Different Acids and Alcohols • Isophthalic Acid • Maleic Acid • Fumaric Acid • Propylene Glycol • Diethylene Glycol • Neopentyl Glycol
Styrene: Crosslinking Genius Dilutes the polyester resin and participates in the crosslinking of the polymers CH=CH 2 Styrene
Low Profile Additives • Ranked from least effective to most effective • Polyethylene • Polystyrene • PolyMethylmethacrylate • Polyvinyl Acetate
Filler (aka Ground Rock) • ATH • CAC03 • Clay • Graphite • Talc • And others.....
ATH vs. CAC03 ATH CAC0 3 Which does your application require?
Fiberglass • Sizing • Filament Diameter • Length • Amount
Additives • Initiators - temperature ranges • Pigments • Release Agents - Ca vs. Zn • Thickeners - Chemical vs. Physical • Antioxidants - Heat Stability • UV Stabilizers
The Composite • Physical Form • Shrink, Density, Cure
BMC Property Range Glass Range, % Specific Gravity Mold Shrinkage, mil/in Flexural Strength, Kpsi Flexural Modulus, psi Tensile Strength, Kpsi Notched Izod, Fppi Water Absorption, %, 24 Hours Arc Resistance, sec Dielectric Strength, V/mil UL 94 Flame Resistance Heat Deflection @ 264 psi, Thermoconductivity, btu/hrs/ft2/0F/in Glass Transition Temperature, Tg 10-30 1.70-2.00 -1.0- +4.5 10-35 1.4-2.2 x 106 3-13 3-33 0.05-0.15 180 - 210 250 - 450 HB – V0 @ 1/32 °F 500+ 1.3-1.7 °C 145-210