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CH3Br, 201009 (2+n)REMPI spectra assignments for region 66000 – 70000 cm-1

CH3Br, 201009 (2+n)REMPI spectra assignments for region 66000 – 70000 cm-1 agust, heima,...Sept09/CH3Br-Overall-021009km-201009ak.pxp agust,www,...Sept09/PPT-201009ak.ppt. Causley and Russel, JCP, 62(3), p:848, (1975):. See next slide. Causley and Russel, JCP, 62(3), p:848, (1975):. cm -1.

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CH3Br, 201009 (2+n)REMPI spectra assignments for region 66000 – 70000 cm-1

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  1. CH3Br, 201009 (2+n)REMPI spectra assignments for region 66000 – 70000 cm-1 agust, heima,...Sept09/CH3Br-Overall-021009km-201009ak.pxp agust,www,...Sept09/PPT-201009ak.ppt

  2. Causley and Russel, JCP, 62(3), p:848, (1975): See next slide

  3. Causley and Russel, JCP, 62(3), p:848, (1975): cm-1

  4. 67273 66502 68877.6 66020 68661 nm agust, heima,...Sept09/CH3Br-Overall-021009km-201009ak.pxp

  5. nm

  6. http://webbook.nist.gov/cgi/cbook.cgi?ID=C74839&Units=SI&Mask=800:

  7. i.e. The bands 66502,67273 and 68877.6 cm-1 are [3/2]5p;0, ni <-<- Ground state; i =3,2,1 – transitions, i.e. Correspond to transition to vibrationally excited states

  8. 1/2 : : : 3/2 : : 68877.6 (1,0,0,...) 68661 (0,0,0,...) (1/2)5p;0 67273 (0,1,0,...) CH3Br* 66502 (0,0,1,...) 66020 (0,0,0,...) (3/2)5p;0 Y´ (v1´,v2´,v3´,...) Y (v1´´,v2´´,v3´´,...)= (0,0,0,...) CH3Br

  9. Prediktions for Y´+ ni´; i = 1,2,3 spectra:

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