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Learn about molecular vibrations, wave frequency, spectrometer types, sample preparation, peak identification, and Fourier transform in IR and Raman spectroscopy.
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Infrared Spectroscopy Terry A. Ring Chemical Engineering University of Utah
Molecular Vibrations • Mass on a spring • Vibration Frequency • ν=c/λ • Wave number =1/ λ
Spectrometer • Single Beam • Dual Beam • with Reference • Gas, Liquid & Solid • Sample Cells • Powder mixed with KCl to make pellet • Reflection off surface of Sample • Attenuated Total Reflection Sample Sample
Spectrum • Peak Identification
Spectrum • Peak Identification • Valence Vibrations • Bending Vibrations
Fourier Transform IR • Mixing light from • Fixed mirror • Moving mirror
Raman Spectroscopy • Laser Light Illumination • Scattered Light Spectra Observed