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Explore the equilibrium and stability criteria in one-component systems, understanding the balance for isolated systems and moving fluids. Learn the fundamentals of stability through entropy and energy considerations. Investigate the criteria for constant temperature, volume, and pressure.
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Chapter 5. Equilibrium and Stability in one Component Systems 國立雲林科技大學化工系 李 榮 和
V = Constant Q = 0 李 榮 和 (The Criteria for Equilibrium: V = U= Constant)
The equilibrium and stability Criteria Equilibrium: dS > 0 ; S = Maxmium Stable: d2S < 0 李 榮 和
The Equilibrium Criteria for moving fluid: T = P = M = Constant , G = Minimum 李 榮 和
(dN = dV = 0) (dU = dN = 0) (dU = dV = 0) 李 榮 和
From q1 < 0 李 榮 和
From q2 < 0 李 榮 和
Prove Cv > 0 at Constant V T = 873.75 V = 0.2933 U = 3799.4 李 榮 和