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This comprehensive overview covers the concept of ionization energy, including the first, second, and third ionization energies of lithium and magnesium. The relationship between ionization energy and electron affinity, along with ionic size trends, is explored in detail. The discussion examines valence versus core electrons and highlights periodic trends that dictate atomic and ionic radius behavior. By analyzing sample problems, learners gain insights into comparing elements like carbon, oxygen, and silicon in terms of atomic radius and ionization energies.
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Unit 4: Atomic and Nuclear Structure Periodic Trends II
Periodic Trends II Ionization Energy: What is ionization energy? First, second and third ionization energies Magnesium as an example … Lithium 1st IE: 513 kJ/mol 2nd IE: 7298 kJ/mol +3 3rd IE: 11815 kJ/mol
Periodic Trends II Ionization Energy: What is ionization energy? First, second and third ionization energies Valence e-vs core e- Lithium 1st IE: 513 kJ/mol 2nd IE: 7298 kJ/mol +3 3rd IE: 11815 kJ/mol
Periodic Trends II Ionization Energy: What is ionization energy? First, second and third ionization energies Valence e-vs core e- Lithium Magnesium 1st IE: 513 kJ/mol 738 kJ/mol +3 2nd IE: 7298 kJ/mol 1451 kJ/mol 3rd IE: 11815 kJ/mol 7732 kJ/mol
Periodic Trends II Ionization Energy: What is ionization energy? First, second and third ionization energies Valence e-vs core e- Lithium Magnesium Aluminum 1st IE: 513 kJ/mol 738 kJ/mol 577 kJ/mol 2nd IE: 7298 kJ/mol 1451 kJ/mol 1817 kJ/mol 3rd IE: 11815 kJ/mol 7732 kJ/mol 2745 kJ/mol
Periodic Trends II Ionization Energy: Periodic trends Why why why??? Exceptions
Periodic Trends II Electron Affinity: What is electron affinity? Ionization energy in reverse … Periodic trend Relationship between ionization energy and electron affinity Why why why???
Periodic Trends Ionic Size: What is ionic radii and how does it compare to atomic radii? Li+ F Li F- 78 pm 71 pm 152 pm 133 pm
Periodic Trends Ionic Size: The periodic trend is the same as that of atomic size
Periodic Trends Other Trends you probable already know about: Valence electrons, ion formation, metals vs nonmetals, and reactivity alkali metals Real alkali metals AP: Why does the reactions show below form NaCl and not NaCl2? Use ionization energies in your explanation. Na + Cl2 NaCl
Periodic Trends II Sample Problems: Compare the elements C, O and Si. Place in order of increasing atomic radius. Which has the largest ionization energy and why? Which has the more negative electron affinity, O or C?