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IPA 2007 – Project funded by the European Union

IPA 2007 – Project funded by the European Union. IPA 2007 Chemical Safety in Croatia Technical Assistance Project. EU Seveso II Directive 96/82/EC Named substances & Categories of substances. 2.3 Activity workshop Angeliki Tsatsou Dritsa Chemist TA Key Expert 2 Zagreb 16-17 June 2011.

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IPA 2007 – Project funded by the European Union

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  1. IPA 2007 – Project funded by the European Union IPA 2007Chemical Safety in CroatiaTechnical Assistance Project

  2. EU Seveso II Directive 96/82/ECNamed substances & Categories of substances 2.3 Activity workshop Angeliki Tsatsou Dritsa Chemist TA Key Expert 2 Zagreb 16-17 June 2011

  3. EU Seveso II Scope I Scope: establishments where dangerous substances are present in excess of some specific quantity thresholds • Establishments: the whole area under the control of the Operator where dangerous substances are present • Operator: operates/holds the establishment or has decisive economic & executive power in technical operation

  4. EU Seveso II Scope II • Presence of substance: actual, or anticipated or may generated during loss of control in an industrial process (raw material, product, by product, residue, intermediate, or those to be generated in an accident) • Dangerous substance: a substance or mixture or preparation listed in Annex I of Seveso II

  5. Named substancesAnnex I Part 1 • Ammonium nitrate (note 1) • Ammonium nitrate (note 2) • Ammonium nitrate (note 3) • Ammonium nitrate (note 4) • Potassium nitrate (note 5) • Potassium nitrate (note 6) • Bromine • Chlorine

  6. Named substancesAnnex I Part 1 • Nickel compounds in inhaled powder form (nickel monoxide, nickel dioxide, nickel sulphide, trinickel disulfide, dinickel trioxide) • Ethyleneimine • Fluorine • Formaldehyde (concentration =>90% • Hydrogen

  7. Named substancesAnnex I Part 1 • Hydrogen chloride (liqulified gas) • Lead alkyls • Liquefied extremely flammable gases (including LPG) • Acetylene • Ethylene oxide • Methanol • 4,4- Methylenebis (2-chloraniline) and/or salts, in powder form

  8. Named substancesAnnex I Part 1 • Methylisocyanate • Oxygen • Toluene diisocyanate • Carbonyl dichloride (phosgene) • Arsenic trichloride (phosphine) • Phosphorous trihydride (phosphine) • Surphur dichloride • Sulphur trioxide • Poly chlorodibenzofuransans and polychlorodibenzodioxins (including TCDD, calculated in TCDDD equivalent

  9. Named substancesAnnex I Part 1 CARCINOGENS at concentration above 5% by weight: • Amino biphenyl and/or its salts • Benzotrichloride • Benzedrine and/or its salts • Bis(chloromethyl0ether • Chloromethylether • 1,2-Dibromoethane • Diethyl sulphate • Dimethyl sulphate

  10. Named substancesAnnex I Part 1 CARCINOGENS at concentration above 5% by weight: • Dimethylcarbamoyl chloride • 1,2-dibromo-3-chloropropane • 1,2-Dimethyly hydrazine • Dimethyl nitrosamine • Hexamethyl phosphoric triamide • Hydrazine • 2-Naphthylamine and/or salts • 4-Nitrodiphenyl • 1,3 Propanesultone

  11. Named substancesAnnex I Part 1 • Petroleum products • Gasolines and naphthas • Kerosenes (including jet fuels) • Gas oils (including diesel fuels, home heating oils and gas blending streams

  12. Categories of substances and preparations Annex I Part 2 1. VERY TOXIC 2. TOXIC 3. OXIDIZING 4. EXPLOSIVE (Note 2, UN/ADR 1.4) 5. EXPLOSIVE (Note 2, UN/ADR 1.4) 6. FLAMMABLE (Note 3 (a) 7. HIGHLY FLAMMABLE (Note 3 (b) (1) 8. EXTREMELY FLAMMABLE ( Note 3(c))

  13. Categories of substances and preparations Annex I Part 2 9. DANGEROUS FOR THE ENVIRONMENT risk phrases i) R50 “ very toxic to aquatic environment” including R50/53 ii) R51/53 “ toxic to aquatic organisms; may cause long adverse effects in the aquatic environment” 10. ANY CLASSIFICATION not covered by dose given and in combination with phrases: (i) R14 “ reacts violently with water” (including R14/15) (ii) R 29 “ in contact with water, liberates toxic gas”

  14. Seveso II substancesinformation resources • Substances Dangerous for the Environment • Substances dangerous to the aquatic environment in the context of the Council Directive 96/82/EC http://mahb.jrc.it/index.php?id=55

  15. Seveso II substancesinformation resources • Substances Dangerous for the Environment • Substances Dangerous to the AquaticEnvironment in the context of the Council Directive 96/82/EC http://mahb.jrc.it/index.php?id=55

  16. Seveso II substances information resources • Carcinogens Single exposure carcinogenic substances in the context of the Council Directive 96/82/EC: • http://mahb.jrc.it/index.php?id=56&dirview=4&fileview=30&eclist=-4-E-

  17. Seveso II substancesclassification • Seveso II substances and preparations are currently classified according to following Directives, as amended: -Dangerous Substances Directive-DSD, 67/548/EEC - Dangerous Preparations Directive DPD, 99/45/EC

  18. Seveso II substancesclassification • Seveso II substances and preparations, after 2015, will be classified according to the new EU Regulation 1272/2008/EC as amended • Annex VI of the above Regulation includes Seveso II substances with harmonized classification

  19. Seveso II substancesclassification Special cases (e.g. wastes) and mixtures that cannot be classified conventionally: their classification is done by EU legislation pertinent to their nature (e.g. EU Waste Code)

  20. Seveso II substancesclassification • Hazard classification of chemicals: According to their intrinsic properties which potentially harm Health and the Environment

  21. Thank you for your attention

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