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Divergent Synthesis of 13-9-Isofurans: Efficient Methods and Applications

This article presents a novel approach to the synthesis of 13-9-Isofurans, detailing a divergent methodology that enhances efficiency and yields. The study explores the use of trityl and tert-butyldimethylammonium fluoride (TBAF) in combination with reagents like para-nitrobenzoic acid (PNBA) and diethyl azodicarboxylate (DEAD) to achieve diverse functionalization of Isofurans. The findings contribute significantly to the field of organic chemistry, offering new insights into synthetic strategies and potential applications of Isofurans in pharmaceuticals.

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Divergent Synthesis of 13-9-Isofurans: Efficient Methods and Applications

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  1. Taber, Douglass F.; Gu, Peiming; Li, Rui. A Divergent Synthesis of the 13-9-Isofurans. Journal of Organic Chemistry (2009), 74(15), 5516-5522.

  2. Tr = trityl = Ph3C

  3. TBAF = tert-butyldimethylammonium fluoride = (n-Bu)4N+ F-

  4. PNBA = para-nitrobenzoic acid DEAD = Diethyl Azodicarboxylate

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