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Substitution reactions at octahedral complexes: the search for mechanism

Substitution reactions at octahedral complexes: the search for mechanism. Begin by determining whether the intimate mechanism is a or d . Table 1. Aquation refers to the reaction. [Co(NH 3 ) 5 X] n+ + H 2 O ? [Co(NH 3 ) 5 (H 2 O)] 3+ + X. Rate constants vary by 6 orders of manitude.

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Substitution reactions at octahedral complexes: the search for mechanism