'Cd ii' diaporamas de présentation

Analytical methods for studying trace metal speciation in the natural environment

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CONNIE HEITMEYER Center for High Assurance Computer Systems Naval Research Laboratory

APPLICATIONS. CONNIE HEITMEYER Center for High Assurance Computer Systems Naval Research Laboratory Washington, DC Workshop on the Verification Grand Challenge SRI International February 21-23, 2005. APPLICATIONS TO PRACTICAL SYSTEMS.

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Isotherms and batch kinetics of the biosorption of cadmium onto pre-treated tridax procumbens

The ash obtained from Tridax procumbens leaves was used to adsorb cadmium from aqueous solution of Cadmium chloride. The sorption process with respect to its metal ion concentration, pH, contact time and particle size on adsorption were studied. The percentage removals with respect to the parameters were also studied. The most effective pH range was found to be 5.8-6.0 for sorption of metal ions. The first order rate equation by Lagergren was tested on the kinetic data and the adsorption process followed first order rate kinetics. Isotherms data were analyzed for possible agreement with Langmuir and Freundlich adsorption isotherms; the model for dynamics of metal ions uptake proposed in this work fitted the experimental data reasonably well for Freundlich adsorption isotherm than Langmuir adsorption isotherm. The correlation coefficients (R2 ) were 0.998 and 0.912 for Freundlich and Langmuir isotherms respectively.

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Synthesis, characterization of tridentate Schiff base metal chelates and their antimicrobial activity

Biological active tridentate Schiff base ligand derived from 2-amino, 4-methyl phenol with indole 3-aldehyde and their Ti(IV), Zr(IV), Cd(II) and Hg(II) metal chelates have been synthesized and characterized on the basis of IR, Elemental analysis, Electronic spectral data, Magnetic measurement, Conductance, 1H NMR and X-ray diffraction method. The Schiff base and its metal complexes have been tested for their antibacterial as well as antifungal activity using disc diffusion methods and the results discussed.

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