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I. Structural Aspects Structural Chemistry Associated with Vacancies: Sc 1 ?x S

Hand-Outs: 42. I. Structural Aspects Structural Chemistry Associated with Vacancies: Sc 1 ?x S. Sc 1.11 S ?? Sc 0.81 S. (S-poor). (S-rich). Sc 1.11 S = ScS 0.9 (vacancies at S). Sc 1 ?x S (vacancies at Sc): S coordination is mixture of. Let u = fraction of 4-coord. S

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I. Structural Aspects Structural Chemistry Associated with Vacancies: Sc 1 ?x S