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第 5 章络合滴定法

第 5 章络合滴定法. Complexometric Titrations. 第五章络合滴定法. 5-1 氨羧络合剂 5-2 络合滴定的基本原理 5-2-1 络合滴定曲线及终点误差 5-2-2 络合滴定终点的检测 5-3 络合滴定的选择性 5-4 络合滴定的应用. 5-1 氨羧络合剂. 氨羧络合剂 — N(CH 2 COOH) 2 基团氨氮、羧氧两种配位原子 —— 络合能力乙二胺四乙酸四元酸 H 4 Y 六元酸 H 6 Y 2+. 滴定分析对化学反应的要求化学计量关系

By darin

(253 views)

第 5 章络合滴定法

By elan

(264 views)

两种金属离子同时被滴定时的终点误差计算

两种金属离子同时被滴定时的终点误差计算. 丁雷. 单一离子滴定的终点误差. pM’ sp =(pc sp +lgK’) Δ pM’=pM’ ep -pM’ sp E t =([Y]’ ep -[M]’ ep )/c M ep =(10 - Δ pM’ [M]’ sp -10 - Δ pY’ [Y]’ sp =(10 Δ pM -10 - Δ pM )/(K’c M sp ) 1/2. 两种离子滴定的终点误差. [Y’] sp =[M’] sp +[N’] sp Δ pY’= Δ p([M’]+[N’])

By ellema

(140 views)

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