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Ch12 Lecture 3 Redox and Ligand Reactions

Substitution Reactions of Square Planar Complexes Kinetics Rate = k 1 [Complex] + k 2 [Complex][Y] The k 2 term is the normal Assoctiative (A) mechanism The k 1 term involves solvent association followed by fast exchange with Y Solvent effects [Solvent] = large and constant

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Soft ligands - PowerPoint PPT Presentation

Ch12 Lecture 3 Redox and Ligand Reactions