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Compressibility

Compressibility. Compressibility Why are gases easier to compress than solids or liquids are?. Compressibility.

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Compressibility

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  1. Compressibility • Compressibility • Why are gases easier to compress than solids or liquids are?

  2. Compressibility • Compressibility is a measure of how much the volume of matter decreases under pressure. When a person collides with an inflated airbag, the compression of the gas absorbs the energy of the impact.

  3. Compressibility • Gases are easily compressed because of the space between the particles in a gas. • The distance between particles in a gas is much greater than the distance between particles in a liquid or solid. • Under pressure, the particles in a gas are forced closer together.

  4. Compressibility • At room temperature, the distance between particles in an enclosed gas is about 10 times the diameter of a particle.

  5. Factors Affecting Gas Pressure • Factors Affecting Gas Pressure • What are the three factors that affect gas pressure?

  6. Factors Affecting Gas Pressure • The amount of gas, volume, and temperature are factors that affect gas pressure.

  7. Factors Affecting Gas Pressure • Four variables are generally used to describe a gas. The variables and their common units are • pressure (P) in kilopascals • volume (V) in liters • temperature (T) in kelvins • the number of moles (n).

  8. Factors Affecting Gas Pressure • Amount of Gas • You can use kinetic theory to predict and explain how gases will respond to a change of conditions. If you inflate an air raft, for example, the pressure inside the raft will increase.

  9. Factors Affecting Gas Pressure • Collisions of particles with the inside walls of the raft result in the pressure that is exerted by the enclosed gas. Increasing the number of particles increases the number of collisions, which is why the gas pressure increases.

  10. Factors Affecting Gas Pressure • If the gas pressure increases until it exceeds the strength of an enclosed, rigid container, the container will burst.

  11. Factors Affecting Gas Pressure • Aerosol Spray Paint

  12. Factors Affecting Gas Pressure • Volume • You can raise the pressure exerted by a contained gas by reducing its volume. The more a gas is compressed, the greater is the pressure that the gas exerts inside the container. V is halved, P doubles

  13. Factors Affecting Gas Pressure • Temperature • An increase in the temperature of an enclosed gas causes an increase in its pressure. • As a gas is heated, the average kinetic energy of the particles in the gas increases. Faster-moving particles strike the walls of their container with more energy.

  14. Factors Affecting Gas Pressure • When the Kelvin temperature of the enclosed gas doubles, the pressure of the enclosed gas doubles.

  15. 14.1 Section Quiz. • 14.1.

  16. 14.1 Section Quiz. • 1. Compared to liquids and solids, gases are easily compressed because the particles in a gas • attract each other. • are spaced relatively far apart. • are very small. • repel each other.

  17. 14.1 Section Quiz. • 2. Gas pressure is affected by • temperature, volume, and the amount of the gas. • temperature, volume, and the molar mass of the gas. • phase diagram, volume, and the size of the container. • temperature, phase diagram, and the mass of the gas container.

  18. 14.1 Section Quiz. • 3. For gases, the SI units for volume (V), pressure (P), and temperature (T) are, respectively, • liters, kilopascals, and °C. • liters, kilopascals, and kelvins. • cm3, kilopascals, and kelvins. • liters, atmospheres, and °C.

  19. The Gas Laws This hot air balloon was designed to carry a passenger around the world. You will study some laws that will allow you to predict gas behavior under specific conditions, such as in a hot air balloon. • How are the pressure, volume, and temperature of a gas related?

  20. Boyle’s Law: Pressure and Volume • If the temperature is constant, as the pressure of a gas increases, the volume decreases. • Boyle’s law states that for a given mass of gas at constant temperature, the volume of the gas varies inversely with pressure.

  21. Boyle’s Law: Pressure and Volume

  22. 14.1

  23. 14.1

  24. 14.1

  25. 14.1

  26. for Sample Problem 14.1

  27. Charles’s Law: Temperature and Volume • Charles’s Law: Temperature and Volume • As the temperature of an enclosed gas increases, the volume increases, if the pressure is constant.

  28. Charles’s Law: Temperature and Volume • Charles’s law states that the volume of a fixed mass of gas is directly proportional to its Kelvin temperature if the pressure is kept constant.

  29. Charles’s Law: Temperature and Volume

  30. 14.2

  31. 14.2

  32. 14.2

  33. 14.2

  34. for Sample Problem 14.2

  35. Gay-Lussac’s Law: Pressure and Temperature • Gay-Lussac’s Law: Pressure and Temperature • As the temperature of an enclosed gas increases, the pressure increases, if the volume is constant.

  36. Gay-Lussac’s Law: Pressure and Temperature • Gay-Lussac’s law states that the pressure of a gas is directly proportional to the Kelvin temperature if the volume remains constant.

  37. 14.3

  38. 14.3

  39. 14.3

  40. 14.3

  41. for Sample Problem 14.3

  42. The Combined Gas Law • The combined gas law describes the relationship among the pressure, temperature, and volume of an enclosed gas. • Allows you to do calculations for situations in which only the amount of gas is constant. The Combined Gas Law

  43. 14.4

  44. 14.4

  45. 14.4

  46. 14.4

  47. for Sample Problem 14.4

  48. 14.2 Section Quiz. • 1. If the volume of a gas in a container were reduced to one fifth the original volume at constant temperature, the pressure of the gas in the new volume would be • one and one fifth times the original pressure. • one fifth of the original pressure. • four fifths of the original pressure. • five times the original pressure.

  49. 14.2 Section Quiz. • 2. A balloon appears slightly smaller when it is moved from the mountains to the seashore at constant temperature. The best gas law to explain this observation would be • Gay-Lussacs's Law. • Graham's Law. • Boyle's Law. • Charles's Law.

  50. 14.2 Section Quiz. • 3. At 46°C and 89 kPa pressure, a gas occupies a volume of 0.600 L. How many liters will it occupy at 0°C and 20.8 kPa? • 0.600 L • 2.58 L • 0.140 L • 2.20 L

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