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University Based Innovation on PEMFC in Turkey

University Based Innovation on PEMFC in Turkey. Anadolu Üniversitesi. Assoc. Prof. Dr. Süleyman Kaytakoğlu Anadolu University Faculty of Engineering and Architecture Department of Chemical Engineering Eskişehir, Turkey February 26-28, 2007. GeT Univation!. I. Part

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University Based Innovation on PEMFC in Turkey

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  1. University Based Innovation on PEMFC in Turkey AnadoluÜniversitesi Assoc. Prof. Dr. Süleyman Kaytakoğlu Anadolu University Faculty of Engineering and Architecture Department of Chemical Engineering Eskişehir, Turkey February 26-28, 2007 GeT Univation!

  2. I. Part Presentation of Dept. of Chemical Engineering AnadoluÜniversitesi

  3. Anadolu UniversityDepartment of Chemical Engineering AnadoluÜniversitesi GeT Univation!

  4. Education • BSc Programme - Since 1970 • MSc Programme - Since 1981 • PhD Programme - Since 1984 AnadoluÜniversitesi GeT Univation!

  5. Academic Staff • Professor 4 • Assoc. Professor 1 • Assist. Professor 8 • Research Assist. 10 • Technicians 2 AnadoluÜniversitesi GeT Univation!

  6. Research Statistics • International Journal Articles 7 • National Journal Articles 5 • Conference Proceeding Articles 9 AnadoluÜniversitesi GeT Univation!

  7. Labs and Equipments • 5000 square meter closed area • 2 million € worth of equipment • One of the well equipped student and • research laboratories in Turkey AnadoluÜniversitesi GeT Univation!

  8. Research Infrastructureat Department of Chemical Engineering • Full Electrochemical System – Solartron • Fuel Cell Test Facilities • GC • GC-MS • Elemental Analyzer • Atomic Absorption Analyzer • HPLC • Fuel Test Lab • FTIR • UV-VIS AnadoluÜniversitesi GeT Univation!

  9. Research Infrastructureat Faculty of Engineering and Architecture • TEM • SEMs (low vac. 0.6nm, EDX,WDX) • AFM • XRDs (Theta-Theta, up to 2000ºC, Rietveld) • XRF • TG-DTA/DSC • BET • FTIR • ICP • Mercury Porosimeter • Rapid prototyping facilities • Well equipped workshop AnadoluÜniversitesi GeT Univation!

  10. II. Part Presentation of University Based Innovation on PEMFC AnadoluÜniversitesi

  11. PEM Fuel Cell AnadoluÜniversitesi Anode Cathode H22H+ + 2e-, U0 =0 V ½ O2 + 2H+ + 2e- H2O, U0 = 1,229 V GeT Univation!

  12. Research Milestones H2 production studies began in 1997. PEMFC activities in Dept. of Chem. Eng. started in 2002. Since then, our PEMFC cell activities have made a peak due to collaborations with Juelich research institute, Germany. AnadoluÜniversitesi GeT Univation!

  13. Fuel Cell Market • 2000 $218 million • 2005 $2.4 billion (The Freedonia Group, Inc.) • 2009 $7 billion (Business Com. Company, Inc.) • 2020 $1.7 trillion (Price Waterhouse-Coopers) • 2030 750,000 jobs (U.S. Dept. of Energy) AnadoluÜniversitesi

  14. Barriers to fuel cell commercialization • High cost of PEMFC components Material costs for a present-day fuel cell stack Material mass Material cost (kg/kW) (US$/kW) Membrane 0.025 120 Electrode 0.082 31.16 Catalyst 0.016 243.2 Bipolar plate 3.3 825 End plate 0.12 0.24 Plastic frame 0.105 0.105 Total 3.684 1219.705 • Lack of fueling infrastructure AnadoluÜniversitesi • Efficient, affordable hydrogen production and storage Kwi Seong Jeong and Byeong Soo Oh Fuel economy and life-cycle cost analysis of a fuel cell hybrid vehicle Journal of Power SourcesVolume 105, Issue 1 , 5 March 2002, Pages 58-65 GeT Univation!

  15. What are we doing for FCs? • Manufacture of Gas Diffusion Layer • MEA production by both conventional and sputter methods • Building up a FC test station upto 5 kW –hardware and software- • PEMFC stack manufacturing – 1 kW • Micro size -both active and passive- DMFC production AnadoluÜniversitesi GeT Univation!

  16. Manufacture of Gas Diffusion Layer Thickness : 300 μm Carbon content : 3-5 mg/cm2 PTFE content : 1-2 mg/cm2 AnadoluÜniversitesi GeT Univation!

  17. MEAProduction AnadoluÜniversitesi Conventional (Pt loading range: 0.1-5 mg Pt/cm2) Sputtered (Pt loading range:0.01-0.1 mg Pt/cm2) GeT Univation!

  18. Building up a FC Test Station AnadoluÜniversitesi GeT Univation!

  19. PEMFC Stack Manufacturing AnadoluÜniversitesi GeT Univation!

  20. DMFC Production AnadoluÜniversitesi GeT Univation!

  21. ResultsforConventionalMEA AnadoluÜniversitesi GeT Univation!

  22. Results for Sputter Based MEA AnadoluÜniversitesi GeT Univation!

  23. Results for Sputter Based MEA AnadoluÜniversitesi GeT Univation!

  24. SEM Image 120 s AnadoluÜniversitesi GeT Univation!

  25. ”The Europe of Knowledge 2020: A vision for university based research and innovation” Liege 25-28 April’04 • Interdisiplinary Approach • Relationship between Higher Education and Research • University – Industry Relationship • The effect of universities in the development of regional development • Mobility of Researchers including between University and Industry • Commercialisation of university based innovation AnadoluÜniversitesi GeT Univation!

  26. Research Collaborations • DAAD (Germany) • Jülich Research Center (Germany) • Technical University of Karlsruhe (Germany) • Solitem Group (Germany) • Louisiana State University (USA) • NTNU, SINTEF and IFE (Norway) • KTH (Sweden) • UNIDO-ICHET (Turkey) AnadoluÜniversitesi GeT Univation!

  27. Industrial Collaborations • Arıkan Machinery Industry GmbH • Demirdöküm DD Heating GmbH • Savronik Defense Industry GmbH AnadoluÜniversitesi GeT Univation!

  28. On Going Projects • Development of a 1 kW PEMFC stack • Maximization of Pt Utilization at PEMFC Electrodes using sputtering method • Optimization of MEA Components • Optimization of operating parameters of PEMFC • Design and Testing ofDMFC • Design and Testing ofPassive DMFC AnadoluÜniversitesi GeT Univation!

  29. Future Projects • Combined Heat and Power (CHP) System for household application • Transportation application of a PEMFC stack AnadoluÜniversitesi • Capture, storage and electrochemical reduction of CO2 to CO • High purity hydrogen production via steam reforming • of natural gas • Membrane for High Temperature PEMFC applications • Non-Pt based electrocatalyst development for FCs GeT Univation!

  30. If you have a problem for which our expertise could be of use, we would like to become your partner - please do not hesitate to contact us! Contact Point Assoc. Prof. Dr. Süleyman Kaytakoğlu Anadolu University Dept. Of Chemical Engineering 26555 - Eskişehir/Turkey Phone: +90-222-3213550/Ext. 6306 Fax: +90-222-3239501 E-mail: skaytako@anadolu.edu.tr AnadoluÜniversitesi GeT Univation!

  31. AnadoluÜniversitesi Thank you for your attention GeT Univation!

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