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This section of the Nuclear Chemistry textbook delves into the concept of radioactivity, detailing how certain elements release radiation. It discusses the three common types of radiation: alpha particles, beta particles, and gamma radiation, highlighting their characteristics and potential biological impacts. The text explains how cells respond to radiation exposure, the dangers posed by different radiation types, and the natural phenomenon of radioactivity in various environments. Key concepts like the strong nuclear force, transmutation, and the implications of radon exposure are also explored.
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Nuclear Chemistry Unit Textbook: Ch. 19 and 20
What is Radioactivity? • Textbook Definition • The process by which certain elements emit (give off) forms of radiation • 3 Common Types of Radiation • Alpha Particles • Beta Particles • Gamma Radiation
All About the Alphas (-particle) • -particles • Fast-flying • Positive Charge (++ or +2) • Essentially a Helium nucleus
All About the Alphas (-particle) • particles are large, and don’t move through solid material easily • Their size gives them the most kinetic energy of the particles, so they can do significant damage • Their positive charge holds them back • particles interact with electrons in the air and very quickly turn into harmless Helium
The Team (Beta Particles) • particles • Fast-flying • Negative Charge • Tiny mass • particles are electrons that have been ejected (kicked out) by an atomic nucleus
The Team (Beta Particles) • Smaller than alpha particles, and usually faster • Able to penetrate light materials such as paper and clothing • They can penetrate human skin, and can kill cells • Once stopped, become part of the material they are in, like any other electron
Gamma () Radiation • Extremely energetic form of electromagnetic radiation • No Mass • No charge • Much more energy than alpha and beta radiation
Gamma () Radiation • No Mass, No Charge – Pure Energy • Can penetrate most materials • Gamma rays destroy cellular molecules • Most dangerous type of radiation to humans • May be used to help fresh produce have a longer shelf life
How Radioactivity OccursNuclear Chemistry—Lecture 2 Textbook Sections 19.2 and 19.3
Radioactivity is a Natural Phenomenon • Radioactivity has been around longer than people • Denver gets about twice as much radiation as New Orleans. Why?
Biological Response to Radiation • How do cells respond to radiation? • Usually, it’s not a big deal • 90+% of your DNA isn’t important • If the DNA damage is really bad, the cell will kill itself (apoptosis—taking one for the “team”)
What Happens if it can’t be fixed? • If the DNA damage can’t be fixed, one of two things can happen • Apoptosis—cell kills itself • Cell Divides • If the cell divides, it produces an identical cell with the same mutation • May lead to cancer • #mutagenproblems#ohnomelanoma #aintnobodygottimeforthat
Radon-222 • Leading source of naturally occurring radiation • Heavier than air—accumulates in basements • Varies based on geology • Some areas of West Virginia and Pennsylvania are highly affected • Over 7000 cases of lung cancer annually due to Radon exposure
Strong Nuclear Force • How do protons (all + charge) hang out in the nucleus when like repels like? • Strong Nuclear Force—an attractive force between nucleons over short distances • Repulsive forces are able to act over longer distances and are also very strong forces Why do large atoms have much more neutrons than smaller atoms?
Strong Nuclear Force • Strong nuclear force acts over very short distances • The bigger the atom, the smaller strong nuclear force • Large atoms require more neutrons to act as a “cement” to keep the protons from repelling one another
Limitations of Neutrons • Neutrons aren’t stable by themselves • Can transform into a proton or electron • Lots of protons around keeps this from happening. • When there are too many neutrons, the protons can’t keep the neutrons in check (like a prison with too few guards) • When neutrons become protons, it causes the atom to eject it
Limitations of Strong Nuclear Force • By Strong Nuclear Force, protons are only attracted to surrounding protons and repelled by all other protons • Like a clique • As more protons are added to the nucleus, atoms become more unstable • More than 83 protons: radioactive
Small Atoms Can Be Radioactive • Carbon-14, an isotope, is radioactive • 8 Neutrons, 6 Protons • Not enough protons to keep the neutrons occupied, resulting in instability
TransmutationNuclear Chemistry Lecture 3 Textbook Section 19.4
Transmutation • When a radioactive nucleus emits an alpha or beta particle, the atomic nucleus changes • If the atomic number changes, the element changes • Transmutation is the changing of one element into another
Release of Energy • Energy is released from a transmutation reaction • Energy from gamma radiation • Kinetic Energy from alpha particle - Most of the energy released is due to the kinetic energy of the alpha particle
Decay • decay is when an element breaks down and releases an particle • The atomic number will decrease by 2 • Atomic mass will decrease by 4
Decay • As a neutron transforms to a proton, it kicks out an electron ( particle) • The atomic number will increase by 1 • The atomic mass will NOT change
Nuclear FissionNuclear Chemistry Lecture 4 Textbook Sections 20.1 and 20.2
What is Nuclear Fission? • Nuclear fission is the splitting of an atomic nucleus • When a neutron is added to U-235 it splits into… • Krypton • Barium • 3 Neutrons
Nuclear Chain Reactions • A nuclear chain reaction occurs when neutrons attack other radioactive atoms in succession
Frequency of Nuclear Chain Reactions • Nuclear chain reactions don’t occur that often in nature • U-235 is a rare isotope (1/139) of U-238, and U-235 is much more fissionable than U-238 • Remember that unstable atoms will be undergoing fission, not the stable ones which are more commonly found in nature
Critical Mass • Not all pieces of U-235 will result in an atomic bomb • If it’s too small, the neutrons will escape and not cause additional fission events • Critical Mass is the required size and weight of a radioactive material for a chain reaction to occur
Applications of Fission • Atomic Bomb • Nuclear Reactors: Nuclear Energy Electrical Energy • 20% of the energy in the US is nuclear energy • Nuclear reactors work by boiling water to produce stream that runs a turbine • 1 kg of Uranium is more powerful than 30 freight car loads of coal
Nuclear Reactors • 3 Required Components • Nuclear Fuel (mostly U-238, 3% U-235) Why? • Water • Heat Transfer into a turbine • Fission plans do NOT release radioactive waste to the environment • Coal does! • Limitation: what do to the with radioactive waste products
Nuclear Fusion • Definition: When small nuclei “fuse” or come together • Opposite of nuclear fission • Mass per nucleon decreases as we move from Hydrogen to Iron • Mass Lost is converted into Energy • Nuclei must be travelling at high speeds in order for fusion to occur to overcome repulsion
The Sun uses Nuclear Fusion • 657 million tons of Hydrogen is fused with 653 million tons of Helium every second • Loss of 4 million tons is converted into energy
The Thermonuclear Bomb • Temperature inside of an atomic bomb is 4-5 times greater than the sun • Hydrogen bombs, or thermonuclear bombs, are typically 1000 times more destructive than the atomic bomb dropped on Hiroshima • How? • Critical mass limits the size of a fission bomb • No such limit exists in fusion bombs