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Detailed Analysis of Amide Vibrational Modes and Nomenclature

This document provides an in-depth examination of the vibrational modes associated with amides, focusing on their nomenclature and the percentages of different stretching and bending contributions. Specifically, it describes Amide I (~80% C=O stretch and ~20% C-N stretch), Amide II (~50% N-H in-plane bend, ~30% C-N stretch, and ~12% C-O in-plane bend), and Amide III (~50% N-H in-plane bend, ~20% C-C stretch, and ~15% C-N in-plane bend). Understanding these modes is essential for studies in organic chemistry and biochemistry.

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Detailed Analysis of Amide Vibrational Modes and Nomenclature

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  1. Mode Nomenclature • Amide I ~80%CO stretch and ~20% CN stretch

  2. Mode Nomenclature • Amide II~50% NH in plane bend + ~30% CN stretch and ~12% CO in plane bend

  3. Mode Nomenclature • Amide III ~50% NH in plane bend + ~20% CC stretch and ~15% CN in plane bend

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