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Entry Task: Jan 24 th Thursday

Entry Task: Jan 24 th Thursday . Question: What distinguishes acids from bases? You have 5 minutes!. Agenda:. Sign off on Ch. 16 sec. 1-4 reading notes In-class practice HW: Acid/Base Properties ws (review from last year). Equation Sheet. I can….

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Entry Task: Jan 24 th Thursday

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  1. Entry Task: Jan 24th Thursday Question: What distinguishes acids from bases? You have 5 minutes!

  2. Agenda: • Sign off on Ch. 16 sec. 1-4 reading notes • In-class practice • HW: Acid/Base Properties ws(review from last year)

  3. Equation Sheet

  4. I can… • Distinguish an acid from a base by its properties. • Explain the difference theories of acid and base behavior of an Arrhenius A/B, Bronsted-Lowry A/B and Lewis A/B. • Use the concentrations of acids and bases to calculate pH and pOH.

  5. Chapter 16Acids and Bases Sections 1 through 4

  6. WarningBlack text slides are embedded notes

  7. Define Acids and Bases • Arrhenius • Acid: Substance that, when dissolved in water, increases the concentration of hydrogen ions. HCl (g) (in water) H+(aq) + Cl-(aq) • Base: Substance that, when dissolved in water, increases the concentration of hydroxide ions. NaOH (s) (in water) Na+(aq) + OH-(aq)

  8. Brønsted-Lowry Acids and Bases • Brønsted–Lowry • Acid: Proton (H+) donor • Base:Proton (H+) acceptor

  9. A Brønsted–Lowry acid… …must have a removable (acidic) proton. HCl(g) + H2O (l)  H3O+ (aq) + Cl- (aq) A Brønsted–Lowry base… …must have a pair of nonbonding electrons. NH3(g) + H2O (l)  NH4+ (aq) + OH- (aq)

  10. If it can be either… ...it is amphiprotic. HCO3− HSO4− H2O

  11. What Happens When an Acid Dissolves in Water? • Water acts as a Brønsted–Lowry base and abstracts a proton (H+) from the acid. • As a result, the conjugate base of the acid and a hydronium ion are formed.

  12. Conjugate Acids and Bases: • From the Latin word conjugare, meaning “to join together.” • Reactions between acids and bases always yield their conjugate bases and acids.

  13. H H Cl O acid base H H Why is HCl an acid? It donates its proton. Why is water a base? It accepts the proton.

  14. + H - H Cl Cl O O conjugate acid conjugate base acid base H H H H What is the conjugate acid and why? H3O+, because it’s now able to donate a proton. What is the conjugate base and why? Cl-, because it’s now able to accept a proton.

  15. O H H H N H acid base H H Why is water an acid? It donates its proton Why is NH3 a base? It accepts a proton.

  16. + H - O H O N N H H base acid conjugate acid conjugate base H H H H H H What is the conjugate acid and why? NH4+, because its now able to donate a proton. What is the conjugate base and why? OH-, because its now able to accept a proton.

  17. NH4+ + OH- NH3 + H2O What is happening here? Looks like NH4+ has lost a proton to OH-, becoming the proton donor- ACID Looks like OH- gained a proton is becomes a BASE When a acid (NH4+) donates a proton becoming NH3, it becomes conjugate base.- because it now able to accept a proton. When a base (OH-) accepts a proton it becoming H2O conjugate acid.- because it now able to donate a proton.

  18. HBr + H2O  H3O+ + Br- What is happening here? Looks like HBr has lost a proton to H2O, becoming the proton donor- ACID Looks like H2O gained a proton is becomes a BASE When a acid (HBr) donates a proton becoming Br-, it becomes conjugate base.- because it now able to accept a proton. When a base (H2O) accepts a proton it becoming H3O+ conjugate acid.- because it now able to donate a proton.

  19. Acid and Base Strength • Strong acids are completely dissociated in water. • Their conjugate bases are quite weak. • Weak acids only dissociate partially in water. • Their conjugate bases are weak bases.

  20. Graphical representation of the behavior of acids of different strengths in aqueous solution. A Strong Acid A Weak Acid

  21. Acid and Base Strength • Substances with negligible acidity do not dissociate in water. • Their conjugate bases are exceedingly strong.

  22. Acid and Base Strength In any acid-base reaction, the equilibrium will favor the reaction that moves the proton to the stronger base. HCl(aq) + H2O(l) H3O+(aq) + Cl−(aq) H2O is a much stronger base than Cl−, so the equilibrium lies so far to the right K is not measured (K>>1).

  23. HC2H3O2(aq) + H2O(l) H3O+(aq) + C2H3O2−(aq) Acid and Base Strength Acetate is a stronger base than H2O, so the equilibrium favors the left side (K<1).

  24. H2O(l) + H2O(l) H3O+(aq) + OH−(aq) Autoionization of Water As we have seen, water is amphoteric. In pure water, a few molecules act as bases and a few act as acids. This is referred to as autoionization.

  25. Ion-Product Constant The equilibrium expression for this process is Kc = [H3O+] [OH−] This special equilibrium constant is referred to as the ion-product constant for water, Kw. At 25°C, Kw = 1.0  10−14

  26. Kw constant Calculate the values of [H+] and [OH-] in a neutral solution at 25°C. [H+] [OH-] = (x)(x) = 1.0x 10-14 (x)2 = 1.0x 10-14 Square root both sides and x = 1.0x 10-7

  27. Kw constant If the [H+] is 1.0x 100 or 1 this means it contains only H+ ions and NO OH- ions If the [H+] is 1.0x 10-1 to 1.0x 10-6 means is contains more H+ ions than OH- ions-therefore an acidic solution

  28. Kw constant If the [OH-] is 1.0x 100 or 1 this means it contains only OH- ions and NO H+ ions If the [OH-] is 1.0x 10-1 to 1.0x 10-6 means is contains more OH- ions than H+ ions-there for a basic solution

  29. Kw constant Indicate whether each of the following solutions is neutral, acidic or basic: [H+] 2 x10-5 M This is an acidic solution [OH-] 2 x10-9 M This is an acidic solution [OH-] 1 x10-7 M This is an neutral solution

  30. Kw constant Calculate the values of [H+] in a (a) solution in which [OH-] is 0.010 M (b) a solution in which [OH-] is 2.0x10-9M. [H+] [OH-] = (x)(x) = 1.0x 10-14 [H+] = 1.0x 10-14 [H+] = 1.0x 10-14 [OH-] [0.010] [H+]= 1.0x 10-12 this is a basic solution

  31. Kw constant Calculate the values of [H+] in a (a) solution in which [OH-] is 0.010 M (b) a solution in which [OH-] is 2.0x10-9M. [H+] [OH-] = (x)(x) = 1.0x 10-14 [H+] = 1.0x 10-14 [H+] = 1.0x 10-14 [OH-] [2.0x 10-9] [H+]= 5.0x 10-6 this is a acidic solution

  32. pH pH is defined as the negative base-10 logarithm of the hydrogen ion concentration. pH = −log [H+]

  33. pH • In pure water, Kw = [H3O+] [OH−] = 1.0  10−14 • Because in pure water [H3O+] = [OH−], [H3O+] = (1.0  10−14)1/2 = 1.0  10−7

  34. pH How does the [H+] concentration affect the kinetic rate law? The rate law is first order, double the concentration of [H+], the rate doubles.

  35. pH • Therefore, in pure water, pH = −log (1.0  10−7) = 7.00 • An acid has a higher [H3O+] than pure water, so its pH is <7 • A base has a lower [H3O+] than pure water, so its pH is >7.

  36. pH These are the pH values for several common substances

  37. Calculate pH If we have a [H+] of 1.0 x10-12, what is the pH? pH = -log (1.0 x 10-12) = pH = -(-12.00) = 12 What is the pH of a solution which has [H+] of 5.0 x10-6? pH = -log (5.0 x10-6) = pH = -(-5.30) = 5.30

  38. Calculate pH If we have a [H+] of 3.8 x10-4, what is the pH? pH = -log (3.8 x10-4) = pH = -(-3.42) = 3.42 What is the pH of a solution which has [H+] of 5.3 x10-9? pH = -log (5.3 x10-9) = pH = -(-8.28) = 8.28

  39. Calculate concentration from pH Calculate the amount of [H+] with a solution with a pH of 3.76 3.76 = -log [H+] Get the negative to the other side -3.76 = log [H+] AntiLog both sides [H+] = -3.76 [H+]= 1.7 x10-4

  40. Calculate concentration from pH Calculate the amount of [H+] with a solution with a pH of 9.18 9.18 = -log [H+] Get the negative to the other side -9.18 = log [H+] AntiLog both sides [H+] = -9.18 [H+]= 6.6 x10-10

  41. Other “p” Scales • The “p” in pH tells us to take the negative log of the quantity (in this case, hydrogen ions). • Some similar examples are • pOH−log [OH−] • pKw−log Kw

  42. Watch This! Because [H3O+] [OH−] = Kw = 1.0  10−14, we know that −log [H3O+] + −log [OH−] = −log Kw = 14.00 or, in other words, pH + pOH = pKw = 14.00

  43. How Do We Measure pH? • For less accurate measurements, one can use • Litmus paper • “Red” paper turns blue above ~pH = 8 • “Blue” paper turns red below ~pH = 5 • An indicator

  44. How Do We Measure pH? For more accurate measurements, one uses a pH meter, which measures the voltage in the solution.

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