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Polymerization Statistics: No Crosslinker Formulation with 85% Conversion Rate

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This analysis presents the polymerization statistics for a formulation without any crosslinkers, yielding an average total conversion of 85%. The degree of polymerization (DP) achieved is 28, resulting in 27,610 chains with no crosslinking present. In contrast, using a formulation with 20% crosslinkers leads to a DP of 174 and 4,484 chains, offering insight into the impact of crosslinkers on polymer architecture. The study reveals significant differences in molecular availability and chain connectivity influenced by crosslinker concentration.

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Polymerization Statistics: No Crosslinker Formulation with 85% Conversion Rate

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  1. Polymerization Stats

  2. 100x100x100 No Crosslinker Formulation with No crosslinker present 4% initiator 100x100x100x.9=900000 molecules Available for RXNs (since 10% are Voids) AVG Total Conversion of 85%

  3. Terms • Degree of polymerization: number of molecules attached to polymer chain • Crosslinks: A molecule on the chain which has four bonds

  4. 100x100x100 No Crosslinker

  5. 100x100x100 Crosslinker (20%)

  6. 100x100x100 Crosslinker (20%)

  7. No Crosslinker Conversion 85% DP 28 Chains 27610 20% Crosslinker Conversion 85% DP 174 Chains 4484 Comparing Cases Usually have around 16% Crosslinker in the formulation

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