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Thermal Physics

Thermal Physics. 13 - Temperature & Kinetic Energy 15 - Laws of Thermodynamics. Assignments. Read 13.2,4,6-10 Read 14.1-4 for review Read 15.1-9 Asgn 13/Q3,5,27 and P32,34,44 15/Q1-3 and P5-8,10,16,21,23,24,32,39,42. Introduction to Thermodynamics Temperature and Heat

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Thermal Physics

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  1. Thermal Physics 13 - Temperature & Kinetic Energy 15 - Laws of Thermodynamics

  2. Assignments • Read 13.2,4,6-10 • Read 14.1-4 for review • Read 15.1-9 • Asgn • 13/Q3,5,27 and P32,34,44 • 15/Q1-3 and P5-8,10,16,21,23,24,32,39,42

  3. Introduction to Thermodynamics • Temperature and Heat • Gas Law Review

  4. Thermodynamics • This is the study of heat and htermal energy. • Thermal properties (heat and temperature) are based on the motion of molecules. This is one part of our studies that relates to Chemistry.

  5. Total Energy • E = U + K + Eint • U: potential energy • K: kinetic energy • Eint: internal or thermal energy • Potential and kinetic energies are specifically for large objects and represent mechanical energy • Thermal energy relates to the kinetic energy of the molecules of a substance.

  6. Temperature and Heat • Temperature is a measure of the average kinetic energy of the molecules of a substance - a measure of how fast the molecules are moving. Unit: oC or K • Temperature is NOT heat! • Heat is the internal energy that is transferred between bodies in contact. Unit: joules (J) or calories (cal) • A difference in temperatures will cause heat energy to be exchanged between bodies in contact When two bodies are at the same temperature, no heat is transferred; this is called Thermal Equilibrium.

  7. Ideal Gas Law (combined Gas Law) • P1V1/T1 = P2V2/T2 • P1,P2: initial and final pressure (any unit) • V1,V2: initial and final volume (any unit) • T1,T2: initial and final temperature (in Kelvin) • Temperature in K = oC + 273.

  8. Sample Problem • An ideal gas occupies 4.0 L at 23oC and 2.3 atm. What will be the volume of the gas if the temperature is lowered to 0oC and the pressure is 3.1 atm?

  9. Ideal Gas Equation • PV = nRT (using moles) • PV = N kB T (using molecules) • P: pressure (Pa) • V: volume (m3) • n: number of moles • N: number of molecules • R: Universal Gas constant (8.31 J/mol K) • kB: Boltzman’s constant (1.38 x 10-23 J/K) • T: temperature (in K)

  10. Sample Problem • Determine the number of moles of an ideal gas that occupies 10.0 m3 at atmospheric pressure and 25oC. • PV = nRT • n = PV/RT • n = 100,00 Pa(10.0 m3) • 8.31 J / molK (25+273K) • n = mol

  11. Sample Problem • Suppose a near vacuum contains 25,000 molecules of helium in one cubic meter at 0oC. What is the pressure? • PV = nRT n = N molecules • NA Avogadro’s # • PV = NkBT • PV = NkBT = 25,000(1.38x10-23J/K)(273K) • V 1m3 • P = 9.42 x 10-17 Pa

  12. The relationship • between the Universal Gas Law Constant, R (8.31 J/mol K) and Boltzman’s constant kB (1.38 x 10 -23 J/K) is… • Na kB = R • 6.02 x 1023 (1.38 x 10-23 J/K) = 8.32 J/molK • mole

  13. Kinetic Theory of Gases • 1. Gases consist of a large number of molecules that make elastic collisions with each other and the walls of the container. • 2. Molecules are separated, on average, by large distances and exert no forces on each other except when they collide. • 3. There is no preferred position for a molecule in the container, and no preferred direction for the velocity.

  14. Average Kinetic Energy of a Gas • Kave = 3/2 kB T • Kave : average kinetic energy (J) • kB : Boltzmann’s constant (1.38 x 10-23 J/K) • T: Temperature (K) • The molecules have a range of kinetic energies; is just the average of that range.

  15. Sample Problem • What is the average kinetic energy and the average speed of oxygen molecules in a gas sample at OoC?

  16. Sample Problem • Suppose nitrogen and oxygen are in a sample of gas at 100oC. • A. What is the ratio of the average kinetic energies for the two molecules? • B. What is the ratio of their average speeds?

  17. Notation Warning! • U is potential energy in mechanics. However, • U is Eint (thermal energy) in thermodynamics • This means that when we are in thermo, U is thermal energy which is related to temperature. When in mechanics, it is potential energy (related to configuration or position).

  18. U is the sum of the kinetic energies of all molecules in a system (or gas). U = N Kave U = N (3/2 kB T) U = n (3/2 R T) Since kB = R/NA Heat added is + Heat lost is - Work on system is - Work by system is + More about U

  19. First Law of Thermodynamics • DU = Q - W • DU : change in internal energy of system (J) • Q: heat added to the system (J). This heat exchange is driven by temperature difference. • W: work done on the system (J). Work will be related to the change in the system’s volume. • This law is sometimes paraphrased as “you can’t win”

  20. Problem #8 • U = Q - W • U = 200 J - 100 J • U = 100 J Heat added is + Heat lost is - Work on system is - Work by system is +

  21. Problem #9 DU = Q - W 45,000 J - 40,000 J = 0 - W W = - 5,000 J

  22. Gas Processes • The thermodynamic state of a gas is defined by pressure, volume, and temperature. • A “gas process” describes how gas gets from one state to another state. • Processes depend on the behavior of the boundary and the environment more than they depend on the behavior of the gas.

  23. D U = 0. Q = W

  24. Isometric/isochoric V is constant W = 0 Isobaric P is constant W = P D V

  25. Work • Calculation of work done on a system (or by a system) is an important part of thermodynamic calculations. • Work depends upon volume change • Work also depends upon the pressure at which the volume change occurs.

  26. Problem #10 W = P D V = 1 atm (.8-.02) m3 W = 1.013x105 N/m2 (.78m3) W = + work done by a gas W = - work done on a gas

  27. Problem #11 U = Q - W 230 = -120 - W W = -350J W = P D V  D V =W/P = -350 J / 1.013 x 105 J/m3 D V =

  28. Work - isobaric

  29. Work is path dependent

  30. Problem #12

  31. Work done by a Gas When a gas undergoes a complete cycle, it starts and ends in the same state. The gas is identical before and after the cycle. There is no identifiable change in the gas. • U = 0 for a complete cycle. However, the environment, has been changed.

  32. Work done by the Gas

  33. #13 Problem • Consider the cycle ABCDA, where • State A: 200 kPa, 1.0 m3 • State B: 200 kPa, 1.5 m3 • State C: 100 kPa, 1.5 m3 • State D: 100 kPa, 1.0 m3 • A. Sketch the cycle. • B. Graphically estimate the work done by the gas in one cycle. • C. Estimate the work done by the environment in one cycle.

  34. A: 200 kPa, 1.0 m3B: 200 kPa, 1.5 m3C: 100 kPa, 1.5 m3 D: 100 kPa, 1.0 m3

  35. 10. (II) Consider the following two-step process. Heat is allowed to flow out of an ideal gas at constant volume so that its pressure drops from 2.2 atm to 1.4 atm. Then the gas expands at constant pressure, from a volume of 6.8 L to 9.3 L, where the temperature reaches its original value. See Fig. 15–22. Calculate (a) the total work done by the gas in the process, (b) the change in internal energy of the gas in the process, and (c) the total heat flow into or out of the gas.

  36. Problem 15/10 Fig. 15-22

  37. (a) No work is done during the first step, since the volume is constant. The work in the second step • is given by (b) Since there is no overall change in temperature, (c) The heat flow can be found from the first law of thermodynamics.

  38. 2nd Law of Thermodynamics • No process is possible whose sole result is the complete conversion of heat from a hot reservoir into mechanical work. (Kelvin-Planck statement.) • No process is possible whose sole result is the transfer of heat from a colder to a hotter body. (Clausius statement.)

  39. Heat Engines • Heat Engines • The Carnot Cycle • Efficiency

  40. Heat Engines • Heat engines can convert heat into useful work. • According to the 2nd Law of T-D, heat engines always produce some waste heat. • Efficiency can be used to tell how much heat is needed to produce a given amount of work. • NOTE: A heat engine is not something that produces heat. A heat engine transfers heat from hot to cold, and does mechanical work in the process.

  41. QH = W + QL Operating Temps: QH and QL New Sign Convention: QH, QL and W are all positive

  42. Efficiency of Heat Engine • In general, efficiency is related by what fraction of the energy put into a system is convereted to useful work. • In the case of a heat engine, the energy that is put in is the heat that flows into the system from the hot reservoir. • Only some of the heat flowing in is converted to work. The rest if waste heat that is dumped into the cold reservoir.

  43. Efficiency of Heat Engine • Efficiency = W/QH = (QH - QC)/QH * • W: Work done by engine on enviroment • QH: Heat absorbed from hot reservoir • QC: Waste heat dumped to cold reservoir • Efficiency is often given as percent efficiency.

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