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IN - S itu study and D evelopment of processes involving nano- POR ous S olids

IN - S itu study and D evelopment of processes involving nano- POR ous S olids. Institute of Physical Chemistry “I.G.Murgulescu” of Romanian Academy Laboratory of Chemical Kinetics.

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IN - S itu study and D evelopment of processes involving nano- POR ous S olids

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  1. IN-Situ study and Development of processes involving nano-PORous Solids Institute of Physical Chemistry “I.G.Murgulescu” of Romanian Academy Laboratory of Chemical Kinetics

  2. INSIDE-PORES mission is “to develop methodologies for the in-situ application of both static and dynamic techniques and their combinations as a tool to probe the evolution of properties, which are relevant to specific processes that involve nanoporous solids, to greatly contribute to the extensive distribution of the relevant scientific knowledge and for INSIDE-PORES to become a focal point for scientists and technicians working in the field of porous materials” PROJECT OBJECTIVES

  3. The Inside Pores SuperTool Real-Time Integrated Infrastructure Reference Materials Validated Predictive Model for referenece materials Real-Word (RW) Materials Validated Predictive Model Properties for RW Materials Predesign Materials Tailoring of Properties of Pre-design Materials

  4. Spectroscopy Microscopy Difraction Neutron Synchrontron Macroscopic Permeability Sorbtion etc. The Inside Pores SuperTool Real-Time European integrated Infrastructure NanoMaterials & Multifunctional Materials Processes

  5. INTEGRATION APPROACH 1st level of integration according to FP6 requirements2nd level - supertool operation3rd level - integration with venture capital4td level - integration with other networks

  6. List of participants Coordinator : Dr. Nick K. KanellopoulosCoordinator organisation: National Center for Scientific Research "Demokritos"Core Groups: 1. Dr. N. Kanellopoulos - National Center for Scientific Research "Demokritos", NCSRD (HL) 2. Dr. D. Jones – Centre Nationale de la Researche Scientifique, CNRS (F) 3. Prof. Dr. Jörg Kärger - University of Leipzig, Department of Interface Physics, UNILEP (D) 4. Prof. E.F. Vansant - University of Antwerp, UA-UIA (B) 5. Prof. N. Quirke - Imperial College, Imperial (UK) 6. Prof. Dr.-Ing. J. Weitkamp - Universität Stuttgart, Institut für Technische Chemie I, USTUTT-ITC (D) 7. Prof. B.C. Hauback - Institute for Energy and Technology, IFE (NO) 8. Prof. F. Kapteijn – TU Delft (DelftChemTech), TU Delft (NL) 9. Prof. F. Rodriguez-Reinoso - Universidad de Alicante- Departamento de Quimica Inorgánica, UALI (E) 10. Prof. A.A.G. Tomlinson - Istituto di Chimica dei Materiali, Consiglio Nazionale delle Ricerch, CNR (I) 11. Dr. E. Kikkinides - Chemical Process Engineering Research Institute-Centre for Research and Technology, CERTH (HL) 12. Prof. J. Caro - University of Hannover-Institut fuer Physikalische Chemie & Elektrochemie, UNIHAN (D) 13. Prof. Michael StØker – SINTEF, SINTEF (NO) 14. Dr. H. C.W.M. Buijs - TNO Industrial Tech. Materials Technology Division, TNO (NL)

  7. List of participants Satellite Groups:1. Dr. Fernando Albertos - REPSOL -YPF SA, REPSOL YPF (E) 2. Dr. Catrine Laroche - Institute Français du Petrol, IFP (F 3. Dr. Roberto Millini - ENI Tecnologie, ET (I) 4. Ing. Francesco Bonino - Centro Ricerche FIAT, CRF (I) 5. Mr J-P. Joulin - Céramiques Techniques et Industrielles, CTI (F) 6. Dr. Stefan Brandt- GRACE GmbH & Co KG, GRACE (D) 7. Mrs R. Marquinez – Porres - FUND.LEIA CDT, LEIA (E) 8. Dr. N. Theophilou - Silver & Baryte, S&B (HL) 9. Mr. Herman Goverse – ECO Ceramics BV, ECO (NL) 10. Mr. F.M. Velterop - Pervatech BV, Pervatech (NL) 11. Prof. V. Kaucic – National Institute of Chemistry Slovenia, NICS (SL) 12. Prof. J. Papp - Central Research Institute for Chemistry, Hungark Academy of Sciences, CRC IC HAS (HU) 13. Prof. A. Jarzebski - Polish Academy of sciences, Institute of Chemical Engineering, IICh PAN (PO) 14. Prof. M. Caldararu – Institute of Physical Chemistry “I.G. Murgulescu” Romanian Academy, IPCRA (RO) 15. Prof. N. Seaton - University of Edinburgh Division of Engineering, UEdin (UK) 16. Prof. D. Enke - Martin-Luther-Uni. Halle-Wittenberg, MLU-Halle (D) 17. Dr. R. Michaelsen - Berlin Neutron Scattering Center, Hahn-Meitner Institute, HMI (D) 18. Prof. Fricke - Würzburg University, Inst. Physics, UNI Wurzburg (D) 19. Prof. P. Adler - Institut de Physique du Globe de Paris, IPGP (F) 20. Prof. V. Milisic - Université de Bordeaux-Lab. de Génie des Procédés Faculté d' Oenologie, LPG (F) 21. Dr. Gary Brian Hix - De Montfort University, DMU (UK) 22. Prof. Jesus Santamaria, Institute of Nanoscience Aragon - INA (E) 23. Prof. K. Richter, Gesellschaft zur Förderung der naturwissenschaftlich-technischen Forschung in Berlin-Adlershof e.V., GNF (D) 24. Mr. F. Llabres -Luengo –SENER, SENER (E) 25. Dr. D. Kehr - Schunk Kohlenstofftechnik GmbH, SKT (D)

  8. Catalytic oxidation Catalytic gas sensors & • Correlation structure-activity in heterogeneous (gas-solid) selective oxidation, oxidative dehydrogenation and ammoxidation of hydrocarbons (particularly C3, C4); • Catalysts for combustion of C1-C4 hydrocarbons and other volatile organic compounds (VOC) for environmental purposes; • Surface dynamics under the influence of operating conditions of catalysts powders or other materials (including ceramics) by AC in situ (“operando”) electrical conductivity measurements (differential step technique DST) - A special cell consisting of two coaxial cylindrical electrodes with powder as the dielectric coupled with monitoring on- line the exit gases ; • Evaluation of mobility / thermal stability on the surface of weakly adsorbed molecules by studies on variation of the apparent dielectric constant of powders in operando conditions (by in situ capacitance measurements) under adsorption/desorption of various gases); M. Caldararu et al, Sensors and Actuators B 30 (1996) 35; M. Caldararu et al, Appl.Surf.Sci. 181 (2001) 255; M. Caldararu et al, Appl. Surf. Sci. 207 (2003) 318; M. Caldararu et al, Appl.Surf.Sci. 211 (2003) 156; Institute of Physical Chemistry “I.G.Murgulescu” of Romanian Academy Laboratory of Chemical Kinetics

  9. Catalyts: • Bulk (single or multicomponet) oxides; • Supported oxides; • Oxide supported noble metal (Pt, Pd) catalysts; • Oxide supports: g-Al2O3, TiO2, SiO2, ZrO2, CeO2 and CeO2-ZrO2 Thermal stability on porous surfaces of weakly adsorbed species (e.g. water, hydrocarbons) Surface reduction/oxidation Surface hydration/dehydration Information to be obtained: Involvement of proton conduction Relations with surface acidity • Examples: • Studying the effects of residual or atmospheric moisture in facilitating/screening adsorption of some reactive gases; • Gas sensing (SnO2, TiO2 based compounds). Institute of Physical Chemistry “I.G.Murgulescu” of Romanian Academy Laboratory of Chemical Kinetics

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