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https://notendur.hi.is/~ agust/rannsoknir/Crete/PPT-131209x Updated : 14.01.14

HBr , 3 S - , J´= 8 & V(m+9). https://notendur.hi.is/~ agust/rannsoknir/Crete/PPT-131209.pptx Updated : 14.01.14. v + max (1/2) = 20*. 3 S - , J´= 8. H + + Br (1/2). H + <- HBr +(v´). ½ <- ½ predictions. v+= 13 17 20. predictions. H + +

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https://notendur.hi.is/~ agust/rannsoknir/Crete/PPT-131209x Updated : 14.01.14

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  1. HBr, 3S-, J´= 8 & V(m+9) https://notendur.hi.is/~agust/rannsoknir/Crete/PPT-131209.pptx Updated: 14.01.14

  2. v+max(1/2) = 20* 3S-, J´= 8 H+ + Br(1/2) H+ <- HBr+(v´) ½ <- ½ predictions v+= 13 17 20 predictions H+ + Br(3/2) Norm- alized Reproducablepeak Accordingto Andreas: Couldbe H+ + Br <- H(n=3) + Br Seeslide 3 v+max (3/2) = 24* 0.47 eV v+= 12 16 20 0.47 eV 3/2 <- 3/2 KER/eV * https://notendur.hi.is/~agust/rannsoknir/Crete/PXP-131209b.pxp https://notendur.hi.is/~agust/rannsoknir/Crete/PXP-131209.pxp; Gr0, Lay0 <= https://notendur.hi.is/~agust/rannsoknir/Crete/XLS-131209a.xlsx

  3. H*(n=3) + Br * https://notendur.hi.is/~agust/rannsoknir/Crete/PXP-131209b.pxp

  4. v+= 20 17 * https://notendur.hi.is/~agust/rannsoknir/Crete/PXP-131209b.pxp; Gr0, Lay0

  5. v+max(1/2) = 20* 3S-, J´= 8 H+ + Br(1/2) H+ <- HBr+(v´) ……½ <- ½ …….3/2 <- ½ v+= 13 17 20 v+= 9 12 14 15 20 H+ + Br(3/2) Norm- alized v+max (3/2) = 24* v+= 13 17 20 24 ……1/2 <- 3/2 …….3/2 <- 3/2 v+= 12 16 20 KER/eV * https://notendur.hi.is/~agust/rannsoknir/Crete/PXP-131209b.pxp https://notendur.hi.is/~agust/rannsoknir/Crete/PXP-131209.pxp; Gr0, Lay0 <= https://notendur.hi.is/~agust/rannsoknir/Crete/XLS-131209a.xlsx

  6. thetwobiggest H+ <-HBr+(v+) peaks (at 2.9 and 3.38 eV) correspondto • v+ (1/2) = 17 for ½ <- ½ and • v+(3/2) = 20 for 3/2 <- 3/2 • accordingtocalculated v+levels • NB: • v+ = 20 for HBr+(3/2) (E =125046 cm-1 ) is verycloseto • v+= 17 for HBr+*(1/2) (E = 124903 cm-1 ) in energy, • (Seenextslide) • -and it closelycorrespondstothe H + Br+ thresholdenergy (1249004 cm-1) • thebiggestpeak (at 3.38 eV) correspondstothe v+max for theHBr+statewell. • Thepeak at 2.9 eVcorrespondstotheaccessable v+max for theHBr+* state.

  7. HBr, V(m+i)´s H+ + Br(1/2) NB: Seemstobeshifted withrespecttootherspectra H+ + Br(3/2) Normalized H+ <- HBr+(v´) V(m+10) V(m+9) V(m+8) V(m+7) V(m+6) V(m+5) V(m+4) KER/eV https://notendur.hi.is/~agust/rannsoknir/Crete/PXP-131209a.pxp ; Gr0 Lay0 <= https://notendur.hi.is/~agust/rannsoknir/Crete/XLS-131209.xlsx

  8. Spectrumshiftedbyabout -0.047 eV Predictions Original spectrum NB: Seemstobeshifted withrespecttootherspectra 3/2 <- 3/2, predictions(?) KER/eV https://notendur.hi.is/~agust/rannsoknir/Crete/PXP-131209a.pxp ; Gr1 Lay1 <= https://notendur.hi.is/~agust/rannsoknir/Crete/XLS-131209.xlsx

  9. HBr +(1/2) peaks 3S-, J´= 8; 0-1(?) H+ + Br(1/2) HBr+(3/2) peaks H+ + Br <- H(n=3) + Br Seeslide 3 H+ + Br(3/2) KER/eV https://notendur.hi.is/~agust/rannsoknir/Crete/PXP-140112.pxp; Lay:0,Gr:0

  10. OldSpectrumshiftedbyabout -0.047 eV Predictions Original/oldspectrum NB: Seemstobeshifted withrespecttootherspectra Newspectrum 3/2 <- 3/2, predictions(?) KER/eV https://notendur.hi.is/~agust/rannsoknir/Crete/PXP-131209a.pxp ; Gr1 Lay1 <= https://notendur.hi.is/~agust/rannsoknir/Crete/XLS-131209.xlsx

  11. HBr, V(m+i)´s H+ + Br(1/2) Newspectrum/V(m+9) H+ + Br(3/2) Normalized H+ <- HBr+(v´) V(m+10) V(m+9) V(m+8) V(m+7) V(m+6) V(m+5) V(m+4) KER/eV https://notendur.hi.is/~agust/rannsoknir/Crete/PXP-131209a.pxp ; Gr0 Lay0 <= https://notendur.hi.is/~agust/rannsoknir/Crete/XLS-131209.xlsx

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