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agust,heima,.....HCl/REMPI/October08/f3D2&Vv8-221208ak.xls

agust,heima,.....HCl/REMPI/October08/f3D2&Vv8-221208ak.xls Agust,www,.... hcl/rempi/October08/f3D2&Vv8-221208ak.ppt agust,heima,..... HCl/REMPI/October08/II for f3D2_W2-281108vhwak.pxp f 3 D 2 <-<- X 1 S +. http://www3.hi.is/~agust/rannsoknir/rempi/hcl/July08/Model-310708ak.ppt :.

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agust,heima,.....HCl/REMPI/October08/f3D2&Vv8-221208ak.xls

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  1. agust,heima,.....HCl/REMPI/October08/f3D2&Vv8-221208ak.xls Agust,www,.... hcl/rempi/October08/f3D2&Vv8-221208ak.ppt agust,heima,..... HCl/REMPI/October08/II for f3D2_W2-281108vhwak.pxp f3D2 <-<- X1S+

  2. http://www3.hi.is/~agust/rannsoknir/rempi/hcl/July08/Model-310708ak.ppt:http://www3.hi.is/~agust/rannsoknir/rempi/hcl/July08/Model-310708ak.ppt: I used expression: • Experimental points • variable = J´ • Fittparameters = a(scaling factor), b (probably • close to 1(?)) , W12´ (interaction parameter) • Known parameters (dertived from Green et al.): • try to fit the functional form on left side of • Equation # to data points for vs J´ to derive • a (b)andW12´ J´

  3. I(35Cl+)/I(H35Cl+)rel Exp. Calc. W12 = 0.1 * (J´(J´+1))0.4 2 3 4 5 6 7 J´

  4. I(35Cl+)/I(H35Cl+)rel Exp. Calc. W12 = W12´= 0.5 since n = 0 2 3 4 5 6 7 J´

  5. IMPORTANT: Let´s find out what are the error limits for the ratio values to • see if the errors for J´= 7 & 8 are abnormally large. • It does not seem to be easy to evaluate parameters such as W12 and beta from • shape analyses of a I(Cl+)/I(HCl+) vs J´ curve precisely, i.e. A large range • of parameters give good fits • According to • W12(max) = 13.2 (based on the J´= 5 interaction) Hence W12 seems to • be a lot smaller than this value • Lets try to use W12 (J´=5) = 13 “agust,heima,.....HCl/REMPI/October08/f3D2&Vv8-221208ak.xls”

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