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Crystal Field Theory

Crystal Field Theory. Molecular Orbital Theory: Donor- Acceptor Interactions. Molecular Orbital Theory: Full ML 6. Molecular Orbital Theory: Simplified. Counting d-electron Configurations. Counting d-electron Configurations. How do we predict/explain transition metal structures?.

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Crystal Field Theory

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  1. Crystal Field Theory

  2. Molecular Orbital Theory:Donor- Acceptor Interactions

  3. Molecular Orbital Theory: Full ML6

  4. Molecular Orbital Theory: Simplified

  5. Counting d-electron Configurations

  6. Counting d-electron Configurations

  7. How do we predict/explain transition metal structures?

  8. Colors and Spectroscopy of Transition Metal Complexes

  9. Sigma Interaction Strength Spectrochemical Series: I- < Br - < Cl- , F- < OH- < OH2 < NH3 < en < CN- < CO

  10. Pi Donor Ligands: Mainly oxides and halides

  11. Mn2+(aq) MnO4-

  12. Pi Acceptor Ligands: CO, CN-, pyridine

  13. Pi Acceptor Ligands and spectroscopy: CO, CN-, pyridine

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