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Explore the foundations of the Kinetic Molecular Theory to understand why gases behave as described by the ideal gas equation. Discover how gas molecules in constant, random motion affect volume, interactions, and collisions. Learn about real gas deviations at low temperatures and high pressures, and how the Van der Waals equation corrects for them.
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Kinetic Molecular Theory WHY do gases behave the way the ideal gas equation says they do?
Gases consist of a large # of molecules that are in constant, random motion • The volume of the molecules is negligible compared to the total volume of the gas • Gas molecules do not attract or repel each other • Collisions are perfectly elastic – energy is not transferred between molecules during collisions • The average kinetic energy is proportional to the temperature of the system
Real Gas Deviations • Low temperature and High pressure Deviate because – 1. Gas molecules do have volume 2. Gas molecules do attract/repel
Van der Walls equation • Corrects for real gases P + n2a V – nb = nRT V2