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This presentation summary details the findings and ongoing efforts related to mercury studies conducted by the North Carolina Division of Air Quality (DAQ). It highlights significant research efforts in Eastern North Carolina, including the Waccamaw Study and the Charlotte-Mecklenburg Air Mercury Study. Key findings include elevated mercury levels in ambient air and fish, the impact of chlor-alkali plants, and trends in wet deposition. Future plans include continued monitoring and analysis to better understand mercury emissions, wet deposition, and their relationship with local meteorology.
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UPDATE ON DAQ’S AIR QUALITY MEASUREMENTS & MERCURY STUDIES NC DENR/DAQ Mercury/CO2 Workshop Raleigh, NC April 19, 2004 Steve Schliesser Todd Crawford NC Division of Air Quality
Presentation Summary • DAQ Hg studies in Eastern NC - Waccamaw Study - Hg from Wet Deposition - Ambient Air Hg near Chlor-alkali Plant • Charlotte-Mecklenburg Air Hg Study - Four locations in 2002 & 2003 • Summary / Conclusions & Plans
Drivers for DAQ Hg Studies in Eastern NC • Blackwaters sensitive to Hg • 1970 – Cited Hg in Cape Fear River fish • Hg in Fish up to 1.5 ppm • Hg in H2O 10X Safe Drinking Level • Hg in Humans - 3.4 ppm in Blood of Fish Eaters, 10X > Non Fisheaters - 34 ppm in Hair of Fish Eaters - Some of Highest Levels Recorded in US • Discovery of more widespread Hg issues
Mercury Deposition Network (MDN) in Eastern NC • 2 MDN Sites in Eastern NC for Wet Deposition and Ambient Air Monitoring Starting in 1996 • Annual Wet Deposition Data from 9,000-19,000 ng/m3 • Noticeable Reduction Trend from 1998-2002
MDN US Network in 1999 (NC08 = Lake Waccamaw site, NC42 = Pettigrew State Park site.)
. Mercury Wet Deposition, as Volume-Weighted Avg Concentration (ng/L) by Season, Site & Year.
Mercury in Ambient Air near Waccamaw MDN Site • Total and Speciated Hg Air Monitoring - TGM up to 300 ng/m3 –5 min Avg - TGM Annual Avg 2.3 ng/m3 - TGM Background < 2 ng/m3 - RGM up to 300 pg/m3 – 2 hr Avg - RGM background < 2 pg/m3 • Air with Met Data Argued Chlor-Alkali Plant Main Contributor, Leading to Plant Closing in 1999
Total Gaseous Mercury Measured at Riegelwood Flynn Site in 1999
Observed Relationships between Reactive Gaseous Mercury, Elemental Mercury, & Meteorology
Mecklenburg / Charlotte Ambient Mercury Study in 2002-2003 • EPA NATA Study Predicted Mecklenburg County Atmospheric Mercury Levels in Top 5% of US Counties • Charlotte Surrounded by Mercury Emission Sources: Electric Utilities, Medical Waste Incinerator, Large Industrial Boilers • Given No Prior Data, DAQ Initiated Ambient Air Mercury Monitoring Study for TGM, RGM, Hg0 • Setup 4 Sites around Charlotte - One Near Downtown - Other 3 in Suburbia • Completed Data Collection – Reported in 2004
1996 US Estimated County Median Ambient Mercury Concentrations
1996 Estimated County Median Ambient Mercury Concentrations – NC Counties
Summary & Conclusions • NC has / had relatively high Hg, well above US average, in terms of: - Emissions into ambient air - Measurements in specific ambient airsheds - Modeling in specific ambient airsheds - Wet deposition levels - Fish of selected species - People who eat selected fish species • NC data suggests high humidity could reduce ambient RGM, while promoting wet deposition
Future Plans • Finalize Charlotte Area Ambient Mercury Monitoring Study Report • Consider Arrangements for New Hg Study in Piedmont, including: - MDN Site(s) for wet deposition, - Ambient Air Hg and Meteorological Monitoring - Assessing Relationship Between Hg Emissions, Wet Deposition, Meteorology, & Ambient Air Levels