'Phthalocyanine' diaporamas de présentation

Coupling Single Molecule Magnets to Ferromagnetic Substrates. TbPc 2 (Terbium- Phthalocyanino ) SMM. Double Decker Structure Electronic config . o f Tb: [ Xe ]4f 9 6s 2. Phthalocyanine  C 32 H 18 N 8 . Experimental Setup. Easy axis of Ni: Out of Plane (OP) of Ni film

Research highlight. I. Molecules on surfaces. b. c. 1) Phthalocyanine on (a) Cu(100), (b) Cu(111), and (c) on 2nd layer . 3) Pd pincer complexes on Cu(111). a. a. b. 2) TetraPhenylPorphyrin on Au(111) prepared at LT (a) and RT (b).

3-Nitrophthalic anhydride was reacted with urea and cobalt salt in nitrobenzene under N2 at 185°C and cobalttetraanitrophthalocyanine\n(CoTNP) was produced. Cobalt-tetraaminophthalocyanine (CoTAP) was produced by\nreduction of CoTNP caused by Sodium borohydride under N2(g). CoTAP and chloromethylpolystyrene was refluxed\nin nitrobenzene or DMF at 180 oC for 12h. The mixture was cooled down to reach the room temperature and then\nsolvent removed and the resulting precipitate was washed with water to remove excess CoTAP, and dried it to get a\nlight green solid (CoTAP-linked-polymer). \n