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Presentation at the Particulates meeting in Brussels 27-28 jan 2003

Anders Christensen / Roger Westerholm Department of Analytical chemistry. Presentation at the Particulates meeting in Brussels 27-28 jan 2003. Anders Christensen and Roger Westerholm Dept. of Analytical chemistry, Stockholm university. Anders Christensen / Roger Westerholm

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Presentation at the Particulates meeting in Brussels 27-28 jan 2003

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  1. Anders Christensen / Roger Westerholm Department of Analytical chemistry Presentation at the Particulates meeting in Brussels 27-28 jan 2003 Anders Christensen and Roger Westerholm Dept. of Analytical chemistry, Stockholm university

  2. Anders Christensen / Roger Westerholm Department of Analytical chemistry Determination of PAH • Ultrasonic extraction with acetone • 5 ml solvent for 10 min • Solvent evaporation • reducing solvent volume and change to toluene • Solid phase extraction, SPE • 100 mg Si • elution of a 2 ml fraction containing alifatics and PAH • Analysis on LC-GC-MS

  3. Anders Christensen / Roger Westerholm Department of Analytical chemistry UV-detector LC-GC-MS system GC injection valve Waste HPLC-pump Transfer line LC-column HPLC autosampler PTV injector Backflush valve MS

  4. Anders Christensen / Roger Westerholm Department of Analytical chemistry SRM 1649a Urban dust (National Institute of Standards & Technology, NIST)

  5. Anders Christensen / Roger Westerholm Department of Analytical chemistry SRM 2975 Diesel Particulate Matter (National Institute of Standards & Technology, NIST) X 10 X 10 X 10 X 10 X 10 X 10

  6. Anders Christensen / Roger Westerholm Department of Analytical chemistry Multivariate analysis, Round Robin results To try and see why there are differences in the results between the different labs, we have tryed to do a multivariate analysis, PCA of the data. The results of this experiment are not conclusive since there is not enough data, but there might be some indications that could be intresting to discuss.

  7. Anders Christensen / Roger Westerholm Department of Analytical chemistry Scores plot, UDC results UDC Shell TUG LAT MTC VTT EMPA

  8. Anders Christensen / Roger Westerholm Department of Analytical chemistry Loadings plot, UDC results

  9. Anders Christensen / Roger Westerholm Department of Analytical chemistry Scores plot, EUDC results VTT TUG Shell EMPA MTC LAT

  10. Anders Christensen / Roger Westerholm Department of Analytical chemistry Loadings plot, EUDC results

  11. Anders Christensen / Roger Westerholm Department of Analytical chemistry Particle mass VS humidity

  12. Anders Christensen / Roger Westerholm Department of Analytical chemistry WP 500 Activities • Tasks - PAH analysis of samples from • LDV tests • Alternative fuels • Advanced engines & aftertreatment • Oil consumption • We have received samples from AVL, Volvo and EMPA • The analysis of samples will probably begin during the following weeks • Tests at MTC will be performed in February • We have to decide which samples that are most important to analyse

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