metal-organic compounds

1. , metal-organic compounds Acta Crystallographica SectionE Z =2 T = 296 (2) K Structure Reports Mo Ka radia~?n 0.30 x 0.20 x 0.15 mm 0 I" IJ. = 4.51 mm nine . ISSN1600-S368 Data collection Broker APEXII CCD area-detector 7690 measured reflections .d. . th I] N N' } (II) (APEX2; Broker, 2005) R;n. = 0.025 2 me y pyrl Ine-K I zinc Tmin=0.345,T =0.551 (expected range = 0.318-0.508) R ,II ~ Saeed Dehghanpour ,a* Ali Mahmoudi,b Mehdi Khalaj,b b eJ,nement Sadegh Sall}'anpourc and Mitra Adib R[FZ > 2o(F1] = 0.061 152 parameters .' wR(F1 = 0.144 H-atom parameters constrained Department Chemistry,Alzahra University,PO 8ox t993891176, Vanak, of S = 0.97 .:\P = 1.20 e A-3 Tehran,Iran, bDepartment Chemistry, IslamicAzadUniversity, Karaj8ranch, of 3470 reflections .:\Pmin -1.12 e A-3 = Karaj, Iran, and "Departmentof Chemistry, IslamicAzadUniversity, Sari8ranch, Sari, Ira,! / Correspt>ndence e-mail: Dehganpour_farasha@yahoo.com T a bl e 1 Received October2007; accepted20 October 2007 1; Selected geometric parameters (A, 0). .Zn1-N1 1..089 (5) Zn1-a1 2.1992(15) Keyindicators: single-crystal X-raystudy; T. 296 K; meanI1(C-Q .0.009 A; Zn1-N2 2.064(5) Zn1-02 2.2167(17) R fact9r .0.061; wR factor. 0.144; data-to-pararneter ratio. 22.8. N1-Zn1-N2 80.22(19) N2-Zn1-a2 110.03 (15) N2-Zn1-a1 119.49 (14) N1-Zn1-a2 10922 (14) In the title complex, [ZnCI2(C12H9INz)], the ZnII atom has a N1-Zn1-CI1 118.63 (14) a1-Zn1-02 114.51(6) distorted tetrahedral coordination. The organic ligand is bidentate, coordinating the ZnII atom via the two N atoms. Data collection: APEX2 (Bruker, 2005); cell refinement: APEX2; data reduction: APEX2; program(s) used to solve structure: " SHELXTL (Sheldrick, 1998); program(s) used to refine structure: Related literature SHELXTL; molecular graphics: SHELXTL; software used to For related literature, see: Arnirnasr et al. (2002); Ittel et al. prepare material for publication: SHELXTL. (2000); Yamada (1999); Britovsek et aL (1999); Small et aL (1998). SD acknowledges the Alzahra University R~earch Council for partial support of this work. I <~=>~ -0- Supplementar~ data .and figures for this paper are available from the N", /N ~ Ii I ~~n IUCr electronic archives (Reference: SJ2381). Zn ,:~:,. \ References CI CI Amimasr, M., Mahmoudkhani, A. H., Gorji, A., Dehghanpour, S. & Bijanzadeh, H. R. (2002). Polyhedron, 21, 2733-2742. .Brit9vsek, G. J. P., Broce, M., Gibson, V. C., Kimberley, B. S., Maddox, P. J., E .I Mastroianni, S., Mctavish, S. J., Redshaw, C., Solan, G. A., Stromberg, S., xpenmenta White, A. J. P. & Williams, D. J. (1999). 1. Am. Chem. Soc. 121, 8728-8740. C I da Broker (2005). APEX2. Broker AXS Inc., Madison, Wisconsin, USA. rysta ta Ittel, S. D., Johnson,L. K. & Brookhart, M. (2000). Chem. Rev.100,1169-1205. [ZnClz(CuHoINz)] c = 10.8772(8) A Sheldrick, G. M. (1998). SHELXTL. Version 5.10. Broker AXS, Madison, M.. = 444.38 a = 89.790(2)0 Wisconsin,USA. Triclinic, pI /3 = 72.613(2)0 Small,B. L.,Brookhart, M. & Bennett, A. M. A. (1998).1. Am. Chem.Soc.120, a = 7.5680 (6) A y = 88.926(2)0 4049-4050. b = 8.5363 (6) A V = 670.47(9) A 3 Yamada,S. (1999). Coord. Chem. Rev. 190, 537-555.