Design of Chiral Catalysts for Enantioselective Hydrosilylation of Ketones

Mar 03, 2025

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Learn about the innovative methods and designs for nitrogen, phosphorus, and sulfur-based catalysts used in the enantioselective hydrosilylation of prochiral ketones. Explore the creation of chiral ligands, including N,N- and N,S-ligands with diverse functional groups such as thioureas, Schiff bases, and sulfonamides, for asymmetric C-H and C-C bond formations.

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Design of Chiral Catalysts for Enantioselective Hydrosilylation of Ketones

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Design of Nitrogen, Phosphorus and/or Sulfur-based Catalysts for the EnantioselectiveHydrosilylation of ProchiralKetones. Cecilia Anaya de Parrodi a.) Design of chiral ligands A - G: Wedesign chiral N,N- and N,S-ligands withdifferentfunctionalgroups, i.e, thioureas, Schiff bases, sulfonamides. b.) Asymmetric C-H and C-C bond formationwereperformed.