210 likes | 346 Vues
This guide explores the fascinating relationship between everyday concepts like eggs and the scientific world of chemistry, specifically focusing on mole calculations. Using the "dozen" method, we see how one mole, equivalent to Avogadro's number (approximately (6.022 times 10^{23})), serves as a practical counting unit. Examples include calculating molecular weights (MW) using the periodic table, converting between mass, moles, and molecule counts, and exercises to strengthen understanding. Perfect for chemistry students!
E N D
IN-CLASS simple mole calculations (on board) the dozen method way
EGG WORLD CHEMISTRY WORLD Smallest unit 1 egg 1 molecule Practical Counting unit Mole (The chemist’s dozen) Dozen
Eggs vs. chemistry world (continued) EGG WORLD CHEMISTRY WORLD # of smallest units in practical counting unit 1 mole 6.02217 *1023 1 dozen=12 (Avogadro’s #) grams/mole =gram molecular weight = MW (molecular weight) (ADD) Practical mass unit grams/dozen (WEIGH)
THE ONE PLACE EGG WORLD AND CHEMISTRY WORLD DEVIATE A TEENY BIT: Egg world Chemistry world Mass dozen Mass = molecular weight mol (MW) Just add up atomic masses using Periodic Table in grams Must weigh box of eggs
Mass (grams)= MW=Molecular mol Weight = sum of masses in grams of component elements in a compound . (element masses are average masses taken from Periodic Table)
Example of MW Calculation: What is theMWof methane =CH4 ?? atomic mass (Table) # atoms/molecule product C H 1 4 ~12*1=12 ~1*4 = 4 12.011~12 1.00794~1 Sum = MW = 12+4=16 g/mole
In – class exercise on Molecular Weight (MW) calculations Find the MW of… H2SO4 CaCl2 Cu3(PO4)2 2*1 + 1*32 + 4*16 = 98 g/mol 1*40 + 2*35.4 = 110.4 g/mol 3*63.5 + 2*(1*31 +4*16) = 380.5 g/mol 2 `waters of hydration’ per CaCl2 CaCl2*2H2O 1*40 + 2*35.4 + 2*(2*1 + 1*16)=146.8 g/mol
Another way to view mole calculations (if you are allergic to eggs): the triangleMap Method Moles (n) Weight (w)molecule count (N) ALL ROADS LEAD THROUGH MOLES
The triangle `trick’ Multiply Down Moles (n) Weight (w)molecule count (N) Divide up
mole math the triangle way You always get MWand Avogadro’s # = 6.02*1023 Moles (n) w= n x MW N= n*6.02*1023 If you have moles they multiply !! (because… moles breed whenever they can) Molecule count (N) Weight (w)
reverse mole math the triangle way Moles (n) n= N 6.02*1023 n = w MW Ifyou want moles …don’t let these horny critters multiply…divide them up!!! Weight (w) Molecule count (N)
Trips around the triangle: Nw Given: 100 g/mol =MW Given: chemist’s dozen =1 mol count=6.02*1023 Moles (n) w=n*MW =20* 100 6.02*1023 n= 20 6.02*1023 All roads lead through moles Given molecule count N=20 Weight (w) ? w~3.3*10-21 g
Trips around the triangle: wN Given : chemist’s dozen =1 mol count=6.02*1023 Given: 100 g/mol =MW N=n x 6.02*1023 =200 x 6.02*1023 100 n= w = 200 MW 100 Moles (n) All roads lead through moles Given weight w=200 g Molecule count N ? N=1.2*1024
AN ANECDOTE An `out-of-towner’ visiting NYC for the first time asks Joshua Bell (world’s greatest violinist): “How do you get to the Lincoln Center for the Performing Arts ?” Joshua’s answer (supposedly): “Practice, practice, practice….”
Exercise #3a: mole calculations part 1 • weight per mole (MW): what does a mole • of C6H12O6weigh ? (C=12; H=1; O=16) 6*12 + 12*1 + 6*16 = 180 g/mol 1.1) mole to mass: how many g C6 H12O6 of are present in 0.00555 mole of C6 H12O6? 0.00555 mol * 180 g/mol = 1 g 1.2) mass to mole: how many moles of C6 H12O6 are in 360 g of C6H12O6? 360 g/180 g mol-1 = 2 moles
Exercise #3a: mole calculations part 1 (continued) 1.3) mole to # molecule: how many molecules of C6 H12O6 are in 0.5 mol of C6H12O6 ? 0.5 mol *6*1023 molecules/mol = 3*1023molecules 1.4) mass to # molecules:how many molecules of C6 H12O6 are in 120 g of C6H12O6? (120/180) mol * 6*1023 molecules =4*1023 molecules mol
Exercise 5 part 1 (continued) 1.5) # molecules to moles: how many moles in 3*1024 molecules of C6 H12O6 ? 3*1024 molecules/ 6*1023 molecules/mol = 5 moles 1.6) # molecules to mass: How many grams of C6 H12O6are in 2.0 *1022 molecules of C6 H12O6 ? 2*1022 molecules * 180 g 6*1023 molecules/mol mol =0.0333 * 180 = 6 grams
The gram molecular mass of D form N-methylphenyl-2-propan-2-amine (the active form of ‘crystal meth’) is149.2 g/mol. How many moles of crystal meth are in a typical street `teenth’ = 1/16 of an ounce= 1.80 grams ? (Note: 1 mol count=6.022*1023.) • 7.27*1021 • 0.0121 • 82.9 • 2.48*10-22 • 8.98*1025 • 268.5 • My answer isn’t above
B1-Aflatoxin (MW=328.2 g/mol) is a naturally occurring, horribly toxic poison derived from Aspergillus fungi, a common contaminant in corn. It causes cancer in most humans at the staggeringly low exposure level of 1*1017 molecules. What is the equivalent mass of aflatoxin represented by this count ? (Note: 1 mol count=6.022*1023.) • 3.28*10-15 g • 1.84*10-4 g • 5.45*10-5 g • 5.06*10-10 g • 1.98*10-10 g • 6.02*106 g • My answer isn’t above
Micro chip manufacture requires nearly oxygen-free conditions wherein the concentration of O2is at or below 17 pg/L. Given that the atomic mass of O is16g/mol, about how many molecules of O2 /L does this represent ? Note: 1 mol count=6.022*1023 • 5.4*1024 • 3.5*1022 • 5.3*1022 • 3.2*1011 • 6.4*1012 • 1.9*1013 • My answer isn’t above