Mineral and Rock Resources

1. Mineral and Rock Resources

2. Mineral and Rock Resources Virtually everything we use or build or create in modern life involves rock, mineral and fuel resources taken from the Earth

3. Mineral and Rock Resources From the lectures on Chapter 2, you should remember that just 9 elements account for 99.7% of the composition of the Earth’s crust Oxygen O 46.3% Silicon Si 28.2% Aluminum Al 8.2% Iron Fe 5.6% Calcium Ca 4.1% Sodium Na 2.4% Magnesium Mg 2.3% Potassium K 2.1% Titanium Ti 0.5% total 99.7%

4. Mineral and Rock Resources That remaining 0.3% contains a staggering number of rocks and minerals that are useful to modern society, but only occur in very limited quantities in nature In fact, many resources are extremely rare...

5. Ore Deposits An ore is a rock in which a valuable or useful metal occurs at a concentration sufficiently high, relative to average rocks, to make it economically worth mining There two major factors determining the profitability of the mining an ore: The value of the mineral or metal extracted Its concentration in the ore (The higher the concentration, the richer the ore)

6. Gold Deposits Gold is found in very minute amounts in the crust of the Earth, typically 4 ppb (parts per billion) At several hundred dollars an ounce, gold is economical to mine even at concentrations of ppm (parts per million)

7. Copper Deposits Copper has an average concentration of 100 ppm in the crust (25,000 times more common than gold) Since copper is only worth a fraction of the value of gold, it must have a concentration 100,000 times higher than gold to be economical to mine

8. Ore Deposits So, mining an ore is a matter of economics (mines that do not make money, fail!) If demand climbs and prices rise in response, additional not-so-rich ore deposits may become economical to mine And a fall in demand or prices will cause marginal mines to close

9. Distribution The known economic mineral deposits are very unevenly distributed around the word The U.S. has 50% of the world’s known molybdenum deposits and about 15% of the lead, gold and copper deposits The U.S. is the major world consumer of aluminum, using over 25% of the total produced, but has virtually no domestic aluminum ore deposits

10. Aluminum Ore Deposits The most common aluminum (Al) ore is bauxite It consists largely of the minerals gibbsite Al(OH)3, boehmite and diaspore AlOOH, together with the iron oxides goethite and hematite, the clay mineral kaolinite and small amounts of anatase TiO2 Almost all mine able bauxite deposits are found in the tropics and sub-tropics, such as in Jamaica and Australia

11. Types of Mineral Deposits The major problem is that the U.S. is the major consumer of all metals, but only produces a few metals (in pink)

12. Types of Mineral Deposits Deposits of economically valuable rocks and minerals form in a variety of geologic settings Igneous ore deposits Hydrothermal ore deposits Plate tectonic boundaries Sedimentary ore deposits Stream and weathering ore deposits Metamorphic ore deposits

13. Igneous Ore Deposits Igneous rocks, especially those that formed from magmas that cooled below the surface, can contain a variety of valuable ores For example, platinum, gold and silver are found in igneous rock

14. Igneous Ore Deposits As a magma cools, it can concentrate minerals After they have crystallized, lighter minerals may rise to the top of the magma chamber, while heavier may sink to the bottom For example, a dense mineral like chromite, (Fe, Mg)Cr2O4, concentrates on the bottom of the magma chamber

15. Igneous Ore Deposits Igneous ore deposits may be especially valuable if the rocks are coarse-grained, so that the minerals of interest are more easily removed Pegmatite is the term used to describe coarse-grained intrusions

16. Igneous Ore Deposits Feldspars, which are used in ceramics, are the most common silicate rock in the crust and are commonly found as pegmatites Gemstones, such as beryl, aquamarine, tourmaline, ruby, and emerald, are very rare and are found as pegmatites

17. Hydrothermal Ore Deposits Not all minerals deposits related to igneous activity occur within igneous rock bodies Magmas have water and other fluids dissolved in or associated with them During the later stages of crystallization, the fluids may escape from the cooling magma chamber, by seeping through cracks and pores in the surrounding rock (called the country rock) These fluids carry with them dissolved salts, gases and metals

18. Hydrothermal Ore Deposits These warm fluids can leach additional metals from the rocks through which they pass In time, the fluids cool and deposit their dissolved minerals, creating a hydrothermal ore deposit (which can be obvious veins cutting through the country rock)

19. Hydrothermal Ore Deposits The particular minerals deposited vary with the composition of the hydrothermal fluids and the country rock Many metals are found in hydrothermal ores, such as copper, lead, zinc, gold, platinum, silver and uranium Since sulfur is common in magmatic fluids, many of the minerals created are sulfides, such as galena (PbS) and sphalerite (ZnS)

20. Plate Tectonic Boundaries Plate tectonics plays a major role in creating ore deposits There is a relationship between magmatic and metamorphic activities and the formation of ore deposits These type of activities commonly occur along plate boundaries

21. Plate Tectonic Boundaries (Right) The precious-metal deposits in the western U.S. are predominantly hydrothermal deposits related to magmatic activity associated with plate collision and subduction

22. Plate Tectonic Boundaries (Left) The distribution of molybdenum and copper ore deposits in the American Hemisphere is also directly related to the location of ancient and modern plate boundaries

23. Plate Tectonic Boundaries Hydrothermal vents are found all along the mid-oceanic ridges These vents are nicknamed “black smokers” for the dark clouds of sulfide minerals issuing from them, which create metal-rich muds on the seafloor

24. Sedimentary Ore Deposits Sedimentary ore deposits are typically created by chemical deposition Limestone and dolomite are classic example of sedimentary rocks that are mined for use as building materials, as the major ingredient in concrete and as aggregate (gravel) for roads Evaporites are sedimentary mineral deposits that form when a body of seawater trapped in a shallow sea or lagoon dries up (evaporates) This includes table salt and gypsum

25. Sedimentary Ore Deposits One very special type of sedimentary ore deposit are the banded iron formations, which are the largest source of iron on Earth The structures consist of repeated thin layers of iron oxides, either magnetite or hematite, alternating with bands of iron-poor shale and chert These deposits can run for tens of kilometers

26. Sedimentary Ore Deposits The banded iron formations are only found in a very few places on Earth and only in very old sedimentary rocks, typically 2 billion years old

27. Sedimentary Ore Deposits Their formation is thought to be related to the development of the Earth’s atmosphere The early Earth did not have oxygen in its atmosphere, therefore any iron could not weather into iron oxide (i.e., rust) In the primordial oceans, when photosynthetic organisms began producing oxygen, the oxygen reacted with the iron dissolved in the seawater and cause it to precipitate onto the seafloor

28. Low-temperature Deposits Streams and weathering can concentrate mineral deposits Weathering alone can produce useful ores by leaching away unwanted minerals, leaving a residue enriched with metals of value The aluminum ore, bauxite, is created when lateritic soils are very heavily leached by rainfall, leaving behind the insoluble aluminum minerals

29. Low-temperature Deposits Minerals weathered out of rocks, can be carried as sediment or pushed along the streambed by the current Dense, weathering-resistant minerals, such as gold and diamonds, will concentrate in the streambed Such deposits, mechanically concentrated by water, are called placers

30. Metamorphic Ore Deposits The mineralogical changes caused by the heat or pressure of metamorphism also can produce economic mineral deposits Graphite, a mineral composed solely of carbon, is used in “lead” pencils, in batteries, as a lubricant and many application where its high melting point are of use Marble is a very popular building material because of the beautiful figure in the stone

31. Mineral Resources Metals are extremely important mineral resources Iron is by far the most heavily used metal and fortunately is one of the most common Iron deposits are found all around the world and they are easy to mine, and it is easy to smelt the iron from the ore Iron is used to make iron and especially steel And steel is used to make everything from thumbtacks to ocean liners to machines that are used to make everything else

32. Mineral Resources Aluminum is the second most heavily used metal and is valued for its light weight and strength (most air planes are made of aluminum) It is the third most common element in the crust, but it is tied up in silicate minerals from which it is hard to extract Even the extraction of aluminum from bauxite is a complex and difficult process 3-4% of all electricity produced in the U.S. is used in the production of aluminum

33. Mineral Resources

34. Mineral Resources Copper, lead, zinc, nickel, and cobalt are also important metals that are found in sulfide ores associated with hydrothermal deposits and igneous rocks Copper, lead and zinc are also found in sedimentary rocks Zinc has been mined at several locations near Morristown, Tennessee, but demand for zinc is very low (one zinc mine is in the process of reopening) Zinc was used to coat “tin cans”, but most cans are now made of aluminum

35. Mineral Resources The variety of nonmetallic minerals far out number metals and are a vital part of the world economy For example, consider the very common clay minerals Clay is used for creating fine ceramics, bricks, tiles, in the processing of iron ore, in the oil industry as filtering and deodorizing agents in the refining of petroleum and as drilling muds to protect the cutting bit while drilling oil wells Other uses are in construction, in clarifying water and wine, in purifying sewage, and in the paper, ceramics, plastics, and rubber industries.

36. Mineral Resources Porcelain is a ceramic material made by heating selected and refined materials such as clay in the form of kaolinite to high temperatures Raw materials for porcelain, when mixed with water, form a plastic paste that can be worked to a required shape before firing in a kiln at temperatures between about 1200 and 1400 degrees Celsius

37. Mineral Resources 1.1 billion tons of sand and gravel are used annually in the U.S., especially in making concrete Another 1.6 billion tons of crushed rock are used in construction 30 million tons of quartz sand are used in industry, primarily for glass making More the 1 million tons of marble, granite, sandstone and limestone are used for monuments, building facings and as flagstone

38. Mineral Resources Crab Orchard stone is a rare sandstone quarried from the Crab Orchard Mountain of the Cumberland Plateau Predominately rose in color, this mottled stone is streaked in irregular patterns by different shades of brown

39. Mineral Resources “VERO BEACH, Fla. (AP) -- Matt White, a journeyman pitcher trying to make the Los Angeles Dodgers, could become baseball's first billionaire player. It has nothing to do with his arm. He owns a rock quarry in western Massachusetts. While clearing out a couple acres to build a home, he discovered stone ledges in the ground, prompting him to have the property surveyed. A geologist estimated there were 24 million tons of the stone on his land. The stone is being sold for upward of $100 per ton, meaning there's well over $2 billion worth of material used for sidewalks, patios and the like.”

40. Mineral Supply and Demand From 1945 to 1975, there was a constant growth in the world-wide demand for metals The increase in demand ranged from 2% to 10% per year From 1976 to 1982 there actually was a world-wide decrease in demand for metals (as the world reeled in shock from increased oil prices) Since then, the overall trend is up, but there have been regional slumps associated with regional economic problem

41. U.S. Per-capita Consumption Per-capita consumption of rock and minerals in the U.S. in 2002

42. U.S. Consumption 1900-1990

43. U.S. Consumption 1950-1990 In the U.S., from 1950 to 1990, the population grew by 65%, while consumption grew by 130% In 2003, it was estimated that every American would, over a lifetime, consume 3.5 million pounds of mineral and fuel resources

44. U.S. Consumption The U.S. consumes huge quantities of mineral and rock materials, relative to both its population and its production of resources

45. U.S. Consumption Compared to the world: U.S. produced 2700 metric tons of Al all from foreign ore That is 10.6% of the world supply

46. U.S. Consumption Compared to the world: U.S. consumed 6400 metric tons of Al That is 25.2% of the world supply

47. U.S. Consumption Compared to the world: U.S. consumed 2.4 times more Al than we produced One bright note: we recycle one third of the Al we use (cans!)

48. U.S. Consumption Where production falls short of consumption, the U.S. must import to meet domestic needs Low domestic production does not mean that the U.S. is conserving its own resources Rather it indicates that the U.S. does have a resource or that it is not economic to mine The U.S. economy is very dependent on imports

49. U.S. Imports

50. Cobalt Cobalt is a hard, lustrous, silver-gray metal Cobalt minerals have been used for centuries to impart a rich blue color to glass, glazes, and ceramics Today, it is used in the preparation of magnetic, wear-resistant, and high-strength alloys and its compounds are used in the production of inks, paints, and varnishes