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Discover and understand each of the seven crystal structures in detail, from their composition to unique properties and applications.
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Solution • Homogeneous mixture made up of at least one solute dissolved in the solvent
Solute • Substance being dissolved • Portion in lesser molar amount
Solvent • Substance doing the dissolving • Portion in greatest molar amount
Colloid • Slightly larger particles • Light passes & particles stay suspended
Suspension • Even larger particles • Particles block or reflect light
Tyndall Effect • Because light reflects off suspended particles, the light ray can be seen from the side
Size Comparison • Solution < Colloid • Colloid < Suspension
Soluble • When one substance (solute) dissolves in another (solvent)
Solubility • The amount of one substance (solute) dissolved in another (solvent)
ConcentratedSolution • A solution with a relatively large amount of solute dissolved
Concentration • The amount of solute dissolved into solution
Dilute Solution • A solution with a relatively small amount of solute dissolved
Saturated Solution • A solution with the maximum amount of solute dissolved in the solution
Unsaturated Solution • A solution with less than the maximum amount of solute dissolved in solution
Supersaturated Solution • A solution with greater than the maximum amount of solute dissolved in solution
Solution Measures • Concentration • Molarity • Molality • Mole Fraction
Percent Solution • Mass of one portion per the total mass, all times 100 % • %soln = ma/mtotal x 100 %
Molarity • Moles of solute per liter of solution • M = molessolute/Lsoln
Molality • Moles of solute per kilogram of solvent • mo = molessolute/kgsolvent
Mole Fraction • Moles of one portion per total number of moles in the solution • X = molesa/molessoln
Calculate the molarity of a 250 mL solution containing 5.0 g NaOH dissolved in water
Drill: Calculate: • mass of NaCl required to make 1.5 L of 2.0 M NaCl:
Calculate the molality of 69 g of C2H5OH dissolved in 500.0 mL of water
Calculate the mole fraction of each portion when 92 g of C2H5OH dissolved in 144 mL of water
Calculate the molality & mole fraction of a solution containing 46 g of C2H5OH dissolved in 1782 mL of water
Colligative Properties • Properties dependent only on the concentration of particles in solution
Examples • Vapor pressure • Boiling & Freezing points • Osmotic pressure
Drill: • Calculate the VP of a solution containing 36 % glucose (C6H12O6) in water at 29oC: • (VPwater = 30.0 mm Hg)
Vapor Pressure • VPsolution = (VPsolvent)(Xsolvent) • X = mole fraction • VP = vapor pressure
Boiling & Freezing DT = imoK DT = change in BP or FP i = ionic activity K = BP or FP constant
Osmotic Pressure p = iMRT p = osmotic pressure i = ionic activity M = Molarity
Calculate the vapor pressure of a solution containing 150 g C5H10O5 in 162 mL of water at 30oC
Calculate BP & FP of 60.0 g of NaOH in 250 mL waterKBP = 0.512oC/moKFP = -1.86oC/mo
Calculate the osmotic pressure of a solution containing 12 g of NaOH dissolved in 250 mL solution at 27oC
Calculate the vapor pressure of a solution containing 120 g C3H7OH in 144 mL of water at its BP.
Calculate the osmotic pressure of a solution containing 12 g of C4H8O4 dissolved in 750 mL solution at 27oC
Clausius-Claperon Eq (T2)(T1) P2 (T2 – T1) P1 Hv= R ln
VPbenzene Temp (oC) 24.5 27 73.5 127Calculate Hv for benzene:
Drill: Calculate BP & FP of 88 g of CO2 in 750 mL waterKBP = 0.512oC/moKFP = -1.86oC/mo
Calculate the osmotic pressure of a solution containing 29.9 g of CoBr3 dissolved in 7500 mL solution at 27oC
Calculate the vapor pressure of a solution containing 12.0 g C3H8O in 14.4 mL of water at its BP.
180 g C3H8O was dissolved in 180 mL H2O at 27oC making a 1.5 g/mL solution. Calculate X, mo, M, p, VP, BP, & FP.
Drill: Calculate the mass of lead(II)nitrate required to make 250 mL of 0.40 M Pb(NO3)2
300 g C3H6NF was dissolved in 500 g C6H12O at 27oC making a 0.800 g/mL solution. Calculate X, mo, M, p, VP, BP, & FP.
Calculate the molality of a solution that is 33.1 % by mass Pb(NO3)2