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Explore the intricate layers of the Earth's atmosphere in this comprehensive overview. Discover the composition of gases such as nitrogen, oxygen, and trace greenhouse gases, and learn how gravity affects their density and distribution. Gain insights into atmospheric pressure, barometers, and the impact of pollutants like sulfur dioxide and mercury on health and the environment. Understand the significance of the Clean Air Act, acid rain, and ongoing challenges such as the ozone hole. This knowledge is vital for protecting our planet's future.
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The AtmosphereChapter 17 100.1 km Mach 2.9 Watch
What’s In a Breath? 0.934% (Ne, He, H2, Kr, CH4, H2S) 0.036% (a greenhouse gas responsible for planet being warm) <0.03% 20.916% (allows: burning, rust, respiration) 78.084% (reacts with nothing)
And the Other Stuff… Bologna, Italy
“Thickness” of the Atmosphere • Gases zing about at 950 mph (425 m/sec) • Gravity concentrates them near the surface • Density decreases upward • Boiling water at high elevation
Atmospheric Pressure • 1-m Mercury Barometers • Inches or mm of mercury • 29.92 in = 1 atmosphere (avg) at mean sea level • 1 atm ~ 1 bar • The weatherman • Old men and mercury • Aneroid Barometers
Little ozone, temperature decreases rapidly Oxygen Ozone (heated by Sun, absorbs harmful radiation) Air too dense to rise beyond tropopause Temperature in the Atmosphere Heated directly by high-energy X-rays and UV radiation Space Ship One Water vapor, clouds, storms and bad weather (heated by Earth’s radiant heat)
Ozone and You • In stratosphere: • O2 2O O + O2 O3 (ozone) • Ozone very efficient at absorbing UV • In troposphere: • N2 + O2 + heat 2 NO … O3 • Linked to heart disease, cancer, asthma, loss of lung function
CFCs • 1970s, used in almost all refrigerators, air conditioners, propellants in aerosol cans • Stable • Work their way Into atmosphere and Destroy ozone … Come Back!
The Ozone Hole • Not literally a “hole”—more like a male pattern baldness
Other Pollutants • Donora, PA • 27-31 October 1948 • Smog settled over city • Sulfuric acid, nitrogen dioxide, fluorine trapped in valley by stagnant air • 20 dead, 800 animals respiratory illnesses • Plants dead in half-mile radius of steel, zinc works • 1/3 of town’s 14,000 people were sick Donora at noon, Oct. 29, 1948
Clean Air Act of 1970 • Amendment to CAA of ’63 Smog over Shanghai Primary Standards to protect “sensitive” groups: elderly, children, ashtmatics Secondary Standards to protect against decreased visibility, damage to animals, vegetation, crops, and buildings Superscripts=exceptions 1/y
Advancing the Clean Air Act • 1970 Amendments: • Environmental Protection Agency (EPA) to determine the limit of industrial pollutants • Controlling auto emissions by 90% • 1990 Amendments: • Contributors to ozone depletion phased out • Rules on toxic waste and acid rain
The Burning of Hydrocarbons • Form CO2 and/or water during burning
Impurities and Incomplete Burning • Benzene, methane (CH4), carbon monoxide (CO), sulfur dioxide (SO2), nitrogen oxide (NO2) • Mercury in rivers near Kittanning, PA: • Fish at 3.1-19x concentration of mercury than store-bought • Mercury linked to neurological disorders • 5-8x EPA’s acceptable risk depending on age • Minamata Disease Actually, the plant in Seward, PA
Acid Rain • In moist air, you get sulfuric and nitric acids which dissolve in water vapor, fall as rain • pH 7.0 (neutral) • Normal rain pH ~5.7 due to CO2 • 1986, in southern CA a fog reached pH = 1.7
Acid Rain • Too weak to irritate human skin but is devastating to delicate organisms and rock • Damages mountain forests • Germany 1982-1995: 8% unhealthy to 50% SICK • Acidifies lakes causing massive fish kills Acid-rain on forest in Jizera mountains of Czeck Repulic Actually, acid-mine drainage (this is extreme limit)
Rapidly weathers stone monuments • U.S. several billion $/yr repairing damage
Other Toxic Volatiles • Chemicals that readily evaporate into air • Pesticides – some is carried off by wind • Dioxin – formed in backyard burn barrels or wherever plastic polyvinyl chloride is burned • Gets into grass, ruminants • We eat meat: 0.0000000001 g/day • EPA: “at or near levels associated with adverse health effects” • Could cause cancer, birth defects, reproductive and immune disorders V child, blamed on Agent Orange
Particulates and Aerosols • Particulate: Small pieces of solid matter • Aerosols: Small particles suspended in air • Fly ash: Smoke, soot, clay/stuff that can’t burn