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Reaction Types. Chemistry Dr. May. Single Displacement Reaction. A Compound and an element form a compound and an element C + A B CB + A Zn + 2 H Cl ZnCl 2 + H 2 . May I Have This Dance ?. Dancer C steps in to dance with B replacing A
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Reaction Types Chemistry Dr. May
Single Displacement Reaction • A Compound and an element form a compound and an element • C + AB CB + A • Zn + 2 HCl ZnCl2 + H2
May I Have This Dance ? • Dancer C steps in to dance with B replacing A • C + AB CB + A
Zn + 2 HCl 2 Al + 6 HCl Mg + 2 HNO3 Zn + H2SO4 ZnCl2 + H2 2 AlCl3+ 3 H2 Mg(NO3)2 + H2 ZnSO4+ H2 Single Displacement Reactions
Cu + 2 AgNO3 2 Fe + 2 CuSO4 3 Al + 2 CuCl2 Mg + CuSO4 Cu(NO3)2 + 2 Ag Fe2(SO4)3+ 2 Cu 3 AlCl3 + 2 Cu MgSO4 + Cu Single Displacement Reactions
Activity Series Will React With Acid Most Active Li, K, Ca, Na, Mg, Al, Zn, Cr, Fe,Ni, Sn, Pb H Cu, Hg, Ag, Pt, Au HCl + Zn ZnCl2 + H2 Acid Will Not React With Acid Least Active
Driving Force A single displacement reaction is driven by the electron affinity of the elements 2 AgNO3 + Cu Cu(NO3)2 + 2 Ag 2 Ag+1 + 2 NO31 + Cu0 Cu+2 + 2 NO31 + 2 Ag0 Silver wants electrons more than copper 2 Ag+1 + Cu0 Cu+2 + 2 Ag0 Copper is oxidized and silver is reduced
Double Displacement Reaction • Two compounds form two different compounds • AB + CD AD + CB • HCl + KOH KCl + HOH
Let’s Trade Partners • Dancer A takes D and dancer C takes B • AB + CD B + D C CB + AD A
HCl + NaOH 2 HCl + Ca(OH)2 2 KI + Pb(NO3)2 NH4Cl + KOH NaCl + HOH CaCl2 + 2 HOH PbI2 + 2 KNO3 KCl + NH4OH Double Displacement Reactions
Driving Double Displacement • Formation of a precipitate (AgCl ) • Formation of a non-ionized material (H2O) • Formation of a gas (CO2 )
Formation of a precipitate AgNO3 + KCl AgCl + KNO3 Silver chloride precipitates from solution and drives the reaction to the right
Formation of a non-ionized material HNO3 + KOH HOH + KNO3 Water is covalently bonded and does not ionize, driving the reaction to the right.
Formation Of A Gas 2 HNO3 + K2CO3 2 KNO3 + H2CO3 HOH + CO2 Carbonic Acid is unstable and decomposes to form water and carbon dioxide,driving the reaction to the right
No Reaction • If there is no driving force, • Then there is no reaction NaCl + KNO3 No Reaction Na+1 + Cl1 + K+1 + NO31 Na+1 + Cl1 + K+1 + NO31
Synthesis Reaction • Two or more materials combine to form a new compound • A + B AB • 2 H2 + O2 2 H2O
Materials Combine • Two or more materials combine to form a new compound • 2 H2 + O2 2 H2O Hydrogen is oxidized (Loses electrons) Oxygen is reduced (Gains electrons)
Na + Cl2 N2 + 3 H2 4 Na + O2 4 Fe + 3 O2 2 NaCl 2 NH3 2 Na2O 2 Fe2O3 Synthesis Reactions Oxidized Reduced New Compound
Decomposition Reactions • A compound breaks apart to form two or more new materials • AB A + B • 2 KClO3 2 KCl + 3 O2
Compounds Break Apart • A compound breaks apart to form two or more new materials • 2 KClO3 2 KCl + 3 O2
H2CO3 NH4OH H2O CaCO3 H2SO4 H2O + CO2 H2O + NH3 H2 + O2 CaO + CO2 H2O + SO3 Decomposition Reactions
Combustion Reactions • A hydrocarbon compound combines with oxygen to form CO2 plus H2O • CxHy + O2 CO2 + H2O • C3H8 + 5 O2 3 CO2 + 4 H2O
Green House Gas Burning gasoline gives CO2 and H2O • C7H16 + 11 O2 7 CO2 + 8 H2O
CH4 + 2 O2 2 C2H6 + 7 O2 C3H8 + 5 O2 2 C4H10 + 13 O2 C5H12 + 8 O2 CO2 + 2 H2O 4 CO2 + 6 H2O 3 CO2 + 4 H2O 8 CO2 + 10 H2O 5 CO2 + 6 H2O Combustion Reactions Natural Gas Propane Butane Jet Fuel
Hydrocarbon Vs. Hydrogen Fuel 2 H2 + O2 2 H2O C5H12 + 8 O2 5 CO2 + 6 H2O Water is the only product Forms lots of greenhouse gas
The End • This presentation was created for the benefit of our students by the Science Department at Howard High School of Technology • Please send suggestions and comments to rmay@nccvt.k12.de.us