1 / 16

Research on the Photocatalytic Reduction of Carbon Dioxide

Research on the Photocatalytic Reduction of Carbon Dioxide. Supervisor : Xin Feng. Reporter ： Song Guixian. 2012/12/25. 3. 2. 1. 4. Literatures. The solubility of carbon dioxide. Selecting the reductant. Initial ideas of reaction process. Contents. Literatures. Literatures.

zaynah
Télécharger la présentation

Research on the Photocatalytic Reduction of Carbon Dioxide

An Image/Link below is provided (as is) to download presentation Download Policy: Content on the Website is provided to you AS IS for your information and personal use and may not be sold / licensed / shared on other websites without getting consent from its author. Content is provided to you AS IS for your information and personal use only. Download presentation by click this link. While downloading, if for some reason you are not able to download a presentation, the publisher may have deleted the file from their server. During download, if you can't get a presentation, the file might be deleted by the publisher.

E N D

Presentation Transcript

  1. Research on the Photocatalytic Reduction of Carbon Dioxide Supervisor : Xin Feng Reporter：Song Guixian 2012/12/25

  2. 3 2 1 4 Literatures The solubility of carbon dioxide Selecting the reductant Initial ideas of reaction process Contents www.themegallery.com

  3. Literatures

  4. Literatures Commercially produced urea Photocatalytic synthesis of urea www.themegallery.com

  5. Literatures www.themegallery.com

  6. Literatures Figute2.Schematic representation of urea formation over TiO2 supported onzeolite photo catalyst under ultraviolet illumination Basavaraju,V.,G. Photocatalytic Synthesis of Urea from in situ Generated Ammonia and Carbon Dioxide www.themegallery.com

  7. The solubility of carbon dioxide Figure3.S1,methanol;S2,ethanol;S3,acetone;S4,hexane;S5,heptane; S6,cyclohexane; S7,benzene and S8, toluene at 298.15K and 0.1MPa partial gas pressure.Gray bars from Wilhelm and Battino; blank bars from COSMOthermX calculations by using vap file to describe the gas phase; white bars from COSMOthermX calculations by Using energy file to describe the gas phase. www.themegallery.com

  8. Photochemistry of carbonyl compound ①Absorpted hydrogen reaction ②αhomolytic reaction of carbonyl www.themegallery.com

  9. Selecting the reductant Unsaturated bond Easy be oxidized Substance in organics Aldehyde Cyclic structure(except benzene ring) Hydroxy www.themegallery.com

  10. Selecting the reductant

  11. Selecting the reductant www.themegallery.com

  12. Selecting the reductant • Click to add Text • Click to add Text • Click to add Text www.themegallery.com

  13. Initial ideas of reaction process www.themegallery.com

  14. Initial ideas of reaction process Photooxidation of cyclohexanol in literature alcohols: 1-pentanol, 2-pentanol, 3-pentanol, cyclohexanol Product Reaction:under atmospheric oxygen.The catalyst (100 mg), alcohol (10 mL), at room temperature, using a cold mirror with a 500 W ultrahigh-pressure Hg lamp. www.themegallery.com

  15. Initial ideas of experiment project • Reactor condition temperature:25℃～27℃ pressure:1atm catalyst/solution=0.1%～0.2%w/v solvent/reductant=5～9 catalyst selection:determine electrode potential of cyclohexanone/cyclohexanol catalyst preparation:hydrothermal www.themegallery.com

  16. Thank You !

More Related