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Continuous Stirred Tank Reactor

Continuous Stirred Tank Reactor. Problem statement. A chemical reaction takes place in a series of four continuous stirred tank reactors arranged as shown in Fig. 100 lit/hr. 100 lit/hr. 1000 lit/hr. C A0 =1 mol/lit. V 4 C A4 K 4. V 1 C A1 K 1. V 3 C A3 K 3. V 2 C A2 K 2.

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Continuous Stirred Tank Reactor

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  1. Continuous Stirred Tank Reactor

  2. Problem statement A chemical reaction takes place in a series of four continuous stirred tank reactors arranged as shown in Fig

  3. 100 lit/hr 100 lit/hr 1000 lit/hr CA0=1 mol/lit V4 CA4 K4 V1 CA1 K1 V3 CA3 K3 V2 CA2 K2 1000 lit/hr CA1 CA2 CA3 CA4

  4. The chemical reaction is a first order irreversible reaction of the type- A B • The value of the rate constant ki, is different in each reactor. Also, the volume of each reactor Vi is different k

  5. Assumptions: • The system is steady state and unsteady state. • The reactions are in liquid phase. • There is no change in volume or density of the liquid.

  6. Solution

  7. Material balance continued:

  8. Using MATLAB for steady state results function f=fourcstrsteady(x) f=zeros(4,1); %defining constants CA0=1; V1=1000; K1=0.1; %data from table V2=1500; K2=0.2; V3=100; K3=0.4; V4=500; K4=0.3; xa=x(1);xb=x(2);xc=x(3);xd=x(4); %material balance equations: f(1)=(1000*CA0)-(1000*xa)-(V1*K1*xa); f(2)=(1000*xa)+(100*xc)-(1100*xb)-(V2*K2*xb); f(3)=(1100*xb)+(100*xd)-(1200*xc)-(V3*K3*xc); f(4)=(1100*xc)-(1100*xd)-(V4*K4*xd);

  9. Running the following displays the steady state concentrations in the tanks: clc clear all x0=[0,0,0,0]; %initial values x=fsolve(@fourcstrsteady, x0) %fsolve to solve the steadystate

  10. MATLAB for unsteady state results function f=fourcstr(t,x) f=zeros(4,1); %defining constants CA0=1; V1=1000; K1=0.1;%data from the table given V2=1500; K2=0.2;%data from the table given V3=100; K3=0.4;%data from the table given V4=500; K4=0.3;%data from the table given xa=x(1);xb=x(2);xc=x(3);xd=x(4); %defining the differential equations %material balance equations assuming unsteady state f(1)=(1000*CA0)-(1000*xa)-(V1*K1*xa); f(2)=(1000*xa)+(100*xc)-(1100*xb)-(V2*K2*xb); f(3)=(1100*xb)+(100*xd)-(1200*xc)-(V3*K3*xc); f(4)=(1100*xc)-(1100*xd)-(V4*K4*xd);

  11. Running the following code in MATLAB yields the plot depicting the variation of Concentration in each tank: clc clear all x0=[1;0;0;0]; %defining the initial values. [t,x]=ode45(@fourcstr, [0 0.1], x0); %ode45 to solve the unsteady state figure; plot(t,x); %plot function %labelling x and y axes xlabel('time t(hrs)'); ylabel('concentration c(t)');

  12. Steady state result predicted : At steady state, the concentration in tanks 1,2,3 and 4 as predicted by the programme: [CA1 CA2 CA3 CA4]= [0.9091 0.6969 0.6654 0.5856]

  13. Unsteady state results The following variation is predicted with respected to time

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