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Clean Water Plants for Massachusetts May 21, 2008

Clean Water Plants for Massachusetts May 21, 2008. Sam Sofer, PhD, PE Debra Troy, BS John Vallier, BS 973-661-5192 www.cleanairplant.com. Bio-Cascade, Inc Clean Air and Water Systems www.Bio-Cascade.com 800-983-2420 “A Massachusetts business” Distributors and service providers of

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Clean Water Plants for Massachusetts May 21, 2008

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  1. Clean Water Plants for Massachusetts May 21, 2008 Sam Sofer, PhD, PE Debra Troy, BS John Vallier, BS 973-661-5192 www.cleanairplant.com Bio-Cascade, Inc Clean Air and Water Systems www.Bio-Cascade.com 800-983-2420 “A Massachusetts business” Distributors and service providers of Clean Air Plant –CAP™ and Clean Water Plant-CWP™ for New England. Under the authority of Air & Water Solution Inc. Air & Water Solutions PROPRIETARY and CONFIDENTIAL www.cleanairplant.com

  2. Air & Water Solutions Highlights • Founded in 1979, specializing in advanced engineering, biotechnology • US National Science Foundation Award: Small Business Innovation Research • 1996 - Introduction of CAP Clean Air Plant for control of indoor air quality (IAQ), World’s 1st (and only) Biological IAQ Control System • 2002 Business Achievement Award, Technology Merit Award for biological air and water cleaning systems for industry, Environmental Business Journal Air & Water Solutions PROPRIETARY and CONFIDENTIAL www.cleanairplant.com

  3. How it WorksCWP1000 Tank water in Clean air in Treated water out Dirty water in Air & Water Solutions PROPRIETARY and CONFIDENTIAL www.cleanairplant.com

  4. Water Contaminants: four classes 1. Gases: Ammonia, carbon monoxide (CO), ozone, HCN, Cl2 2. Vapors: Volatile Organic Compounds (VOCs) such as ethanol, neurotoxic agents [pesticides and nerve gas], fragrances, solvents, active VOCs (create dust, nasty) • Particulates: Mold, viruses, pathogenic bacteria, smoke, wax particles, entrained oil and solvent particles, dust, silica, quartz • Emulsions: Gasoline/water, tar pit emulsions, steel company emulsions, photographic emulsions, silver, iron Air & Water Solutions PROPRIETARY and CONFIDENTIAL www.cleanairplant.com

  5. Theory Destruction by Total Oxidation or ‘Mineralization’ Propyl Acetate + Oxygen(Air) = Carbon Dioxide + Water C5H10O2 + 6.5O2 = 5CO2 + 5H2O Air & Water Solutions PROPRIETARY and CONFIDENTIAL www.cleanairplant.com

  6. CWP5000 Clean Water PlantCapabilities • Flow rate of dirty water can be turned down from 500 gpm to zero • Can clean to non-detectable (<10 ppb) levels • Can clean very concentrated to pure (1,000,000 ppm) contaminants: • Pesticide liquids/solids • Gasoline, crude oil, MTBE • Alcohols, solvents Air & Water Solutions PROPRIETARY and CONFIDENTIAL www.cleanairplant.com

  7. MTBE and BTEX-Contaminated Groundwater Cleaned Ending Concentrations Air & Water Solutions PROPRIETARY and CONFIDENTIAL www.cleanairplant.com

  8. Biosink at photolab in New York City Air & Water Solutions PROPRIETARY and CONFIDENTIAL www.cleanairplant.com

  9. Free Cells versus Immobilized CellsAdvantages of Immobilization Technology Protective gel layer Immobilized cells Biosupport FREE CELLS are exposed to attack by microorganisms and chemicals from all sides FREE CELLS get washed out during floods or high flow • IMMOBILIZED CELLS • Are back-to-back, not exposed. • Have protective gel layer. • Do not sediment. • Do not wash out. FREE CELLS sediment when pumps fail Air & Water Solutions PROPRIETARY and CONFIDENTIAL www.cleanairplant.com

  10. CWP600 and CWP1000 Air & Water Solutions PROPRIETARY and CONFIDENTIAL www.cleanairplant.com

  11. Total Hydrocarbons Reduced to Non-detectable Levels Air & Water Solutions PROPRIETARY and CONFIDENTIAL www.cleanairplant.com

  12. Air (CAP90) and Water (CWP175) cleaning at contaminated site Air & Water Solutions PROPRIETARY and CONFIDENTIAL www.cleanairplant.com

  13. BioOx destroys VX neurotoxin surrogates Air & Water Solutions PROPRIETARY and CONFIDENTIAL www.cleanairplant.com

  14. Other Applications Air & Water Solutions PROPRIETARY and CONFIDENTIAL www.cleanairplant.com

  15. Air (CAP90) and Water (CWP175) cleaning at contaminated site • LESSONS • To clean water, clean air is needed • Any contaminant cleaned by CAPS may also be cleaned by CWPs Air & Water Solutions PROPRIETARY and CONFIDENTIAL www.cleanairplant.com

  16. CAP90 at Print/Copy Facility “I haven’t heard a reference to [poor] air quality in months, when we used to get daily comments.”Dick Clark,Integrity Printing Air & Water Solutions PROPRIETARY and CONFIDENTIAL www.cleanairplant.com

  17. CAP600 at food company Air & Water Solutions PROPRIETARY and CONFIDENTIAL www.cleanairplant.com

  18. CAP600C at Dental Clinic Air & Water Solutions PROPRIETARY and CONFIDENTIAL www.cleanairplant.com

  19. CAP600 in Hospital Labs Air & Water Solutions PROPRIETARY and CONFIDENTIAL www.cleanairplant.com

  20. CAP5000 at Trash Transfer Station Air & Water Solutions PROPRIETARY and CONFIDENTIAL www.cleanairplant.com

  21. Addition of BioOx® in soluble form eliminates the need for cell growth during BioOxidation. This greatly increases the productivity of contaminant destruction. Air & Water Solutions PROPRIETARY and CONFIDENTIAL www.cleanairplant.com

  22. Destruction of Printers’ Solvents in Water The CAP was used to demonstrate destruction of typical printers’ solvents. Blanket wash, used by printers to clean rollers in the printing presses, contains petroleum naphtha and dipropylene glycol methyl ether. In the figure below, serial injections of about 33,600, 54,300, and 108,500 blanket wash were made in order to determine maximum destruction rates. A two-cartridge system maintains the contamination level to below 100 ppm, a dramatic reduction from the almost 200,000 ppm injected. Air & Water Solutions PROPRIETARY and CONFIDENTIAL www.cleanairplant.com

  23. Hydrocarbon Vapor DestructionIn CAP90, residence time = 0.7 sec Air & Water Solutions PROPRIETARY and CONFIDENTIAL www.cleanairplant.com

  24. Destruction of MTBE in WaterwithCAP Hood 50 Air & Water Solutions PROPRIETARY and CONFIDENTIAL www.cleanairplant.com

  25. Destruction of Nail Salon Solvents The CAP Clean Air Plant was chosen by the Bonita Springs, Florida Fire District in September 2001 as an alternative technology to control the fire hazards associated with the use and storage of nail salon products. The graph below demonstrates destruction of acetone, non-acetone, and liquid monomer solvents. Air & Water Solutions PROPRIETARY and CONFIDENTIAL www.cleanairplant.com

  26. Special Coating Solvent Mix Air & Water Solutions PROPRIETARY and CONFIDENTIAL www.cleanairplant.com

  27. Customer in-line CAP90 DataDec 6-7, 2007 Air & Water Solutions PROPRIETARY and CONFIDENTIAL www.cleanairplant.com

  28. Customer in-line CAP90 DataDec 10-11, 2007 Air & Water Solutions PROPRIETARY and CONFIDENTIAL www.cleanairplant.com

  29. Third Party Verification Oxidation of ethanol vapors in a spiral bioreactor, Lakhwala, Shim, Jung, & Sofer, Journal of chemical technology and biotechnology, 1995, 64, 49-54 Biodegradation of benzene and a BTX mixture using immobilized activated sludge, Lodaya, Lakhwala, Rus, Singh, Lewandowski, and Sofer, Journal of environmental science and health, A26(1), 121-137 (1991) Air & Water Solutions PROPRIETARY and CONFIDENTIAL www.cleanairplant.com

  30. 99.9+% Ammonia destructionCAP902X destruction of pure ammonia from an industrial reactor. No vent to the outside. Air & Water Solutions PROPRIETARY and CONFIDENTIAL www.cleanairplant.com

  31. CAP + CWP = Cost Savings Odor is goneWater is clean Air & Water Solutions PROPRIETARY and CONFIDENTIAL www.cleanairplant.com

  32. Basement Sump Water Treatment by CWP Clean Water Plant, Bedminster NJ Before (Prior to CWP) After (Post CWP Installation) (ppb) (ppb) Percent Destruction Semi Volatiles (BN) 9.25 0.340 96.3 Tentatively Identified Compounds (TIC) including MTBE 150.4 ND 100 Contaminants MTBE 3.20 ND 100 Total BN + TIC 160 0.340 99.8 Air & Water Solutions PROPRIETARY and CONFIDENTIAL www.cleanairplant.com

  33. BioOxidizers are theCleanup Technology of the Future • Treat all types of hazardous pollutants – gas, vapor, liquid, solid • Destroy pollutants at the source • Biological incinerators -- No fuel costs, no CO, no NOX • Economical • Portable Air & Water Solutions PROPRIETARY and CONFIDENTIAL www.cleanairplant.com

  34. Subway Elevator Venting will not de-odorize Motor Room Make-up air Vent above ground Subway Elevator Results Venting is expensive blower costs money to run Venting won’t work odors behave like electrically charged particles, won’t move out Blower Motor Room Air & Water Solutions PROPRIETARY and CONFIDENTIAL www.cleanairplant.com

  35. Subway Elevator Motor Room De-Odorizationusing CAP Clean Air Plants Subway Elevator Results CAPs generate Clean Air Zone no blower or vent ducts required. Saves capital cost and energy. Clean Air Zone Captures charged particles odors are captured by electrical grounding, and then destroyed by enzymes: BioHygienics! Motor Room Air & Water Solutions PROPRIETARY and CONFIDENTIAL www.cleanairplant.com

  36. CAP90 from NYC Subway Elevator Machine Room Air & Water Solutions PROPRIETARY and CONFIDENTIAL www.cleanairplant.com

  37. Smokehouse within Industrial Food Manufacturing Plant CAP55 CAP35 Relative Sizes • CAP90 plus CAP600T met the requirements: • No vent to the outdoors • No smoke or odors outside of the room (total containment) • No activation of plant smoke alarms Air & Water Solutions PROPRIETARY and CONFIDENTIAL www.cleanairplant.com

  38. Wastewater cleaned at Chemical Manufacturing Facility CWP 1000 Air & Water Solutions PROPRIETARY and CONFIDENTIAL www.cleanairplant.com

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