1. Electric dipole Transition moment

6. Elastic and Inelastic Scattering Raman Powerpoint Templates

7. Rayleigh Scattering vs Raman Scattering

10. Interaction between electric field of incident photon and molecule Electric field oscillating with incident frequency vi: Induces molecular electric dipole (p): Proportional to molecular polarizability,  Polarization results in nuclear displacement Classical Raman Physics

11. For small distortions, polarizability is linearly proportional to the displacement • Resultant dipole: Rayleigh Scattering Stokes Raman Anti-Stokes Raman

13. Roto-Vibrational Raman ΔJ = 0 ± 2 LineSpacing 4B

15. Ressonance Raman Scattering effect enhanced by a factor 106

16. Instrumentation

19. Lasers Ar+ ion 488.0 nm & 514.5 nm • Kr+ ion 530.9 nm & 647.1 nm • He:Ne 632.8 nm • Nd:YAG 1064 nm • Diode 630 nm & 980 nm • Resolution < 6 cm-1 → • Laser Linewidth < 1 cm-1 • Wavelength Stabilization is a must have • (most common 785 nm NIR 300mW

22. Holographic notch filter