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Åbo Akademi Process Chemistry Centre

Åbo Akademi Process Chemistry Centre. Activity Review PCC Annual Seminar, August 26, 2011 Mikko Hupa. ÅA PCC Mission.

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Åbo Akademi Process Chemistry Centre

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  1. Åbo Akademi ProcessChemistry Centre ActivityReview PCC Annual Seminar, August 26, 2011 Mikko Hupa

  2. ÅA PCC Mission Detailed understanding of physico-chemical processes in environments of industrial importance in order to meet the needs of tomorrow’s process and product development

  3. ÅA PCC Mission Detailed understanding of physico-chemical processes in environments of industrial importance in order to meet the needs of tomorrow’s process and product development We call our approach Molecular Process Technology

  4. MolecularProcessTechnology • Parallel to other “molecular sciences”, Molecular Biology, Molecular Medicine • Molecular Process Technology should work on: • chemical phenomena and mechanisms at the molecular level • elementary reactions and interactions in complex industrial processes • process models based on detailed physico-chemical understanding • relevant molecular structures for industrial products • environmentally significant components discharged from processes

  5. ÅA-PCC Scientific Advisory Board 2007-2011 • Jean-Claude Charpentier, CNRS/ENSIC/INPL Nancy • JiriJanata, Georgia Institute of Science and Technology, Atlanta, USA • Douglas Reeve, University of Toronto, Canada • Jan Bäckman, Academy of Finland • HeikkiTenhu, Academy of Finland (Univ. of Helsinki) • Jukka Leppälahti, Tekes August 26, 2011

  6. ÅA-PCC Industrial Advisory Board 2011- Heikki Laurila, Outotec Timo Leppä, Chemical Industry Federation of Finland Lars Peter Lindfors, Neste Oil Leena Paavilainen, Metla Ismo Reilama, Metsä-Botnia Bengt-Johan Skrifvars, Top Analytica Kenneth Sundberg, Tikkurila Kari Toivonen, Elomatic Petri Vasara, Pöyry ÖrjanAndersson, Novia IlmoAronen, Raisio Srig-Erik Bruun, Chemigate Håkan Gros, Danisco Heidi Fagerholm, Kemira Lars Gädda, Forestcluster Markku Karlsson, UPM-Kymmene BertelKarlstedt, Nordkalk Nina Kopola, Dynea Eeva-Liisa Lakomaa, Vaisala

  7. Åbo Akademi Process Chemistry Centre Wood and Paper ChemistryProf.Bjarne Holmbom Combustion and Materials Chemistry Prof. Mikko Hupa Wood Chemistry Combustion Chemistry Fibre and Pulping Chemistry Materials Chemistry Paper Chemistry Process Analytical ChemistryProf. Ari Ivaska Catalysis and Reaction EngineeringProf. Tapio Salmi Chemical Sensors Heterogeneous Catalysis Electroactive Materials Chemical Kinetics Environmental and On-line Analysis Chemical Reactor Modelling

  8. PCC 2011

  9. PCC 2011 Senior researchers 4 + 30Doctoral thesis works 45MSc thesisworks 20Support and visitors 26Total participation 130

  10. Personnel by Region of Origin 2010

  11. PCC Conference Travel 2010

  12. Graduate School in Chemical Engineering(GSCE, 2003-2006, 2007-2011, 2012-2015) Nordic Graduate School in Biofuel Science and Technology(biofuelsGS, 2003-2006, 2007-2010) Biomaterial Graduate School (BGS, 2003-2006) Chemical Sensors and Micro Analytical Systems (CHEMSEM, 2003-2006, 2006-2009) Environmental Science and Technology (EnSTe, 2003-2006, 2007-2011) Graduate School for Biomass Refining (BIOREGS, 2010-2013) Graduate School of Materials Research (GSMR, 2003-2006, 2007-2011) Pulp and Paper Science and Technology (PaPSaT, 2003-2006, 2007-2011) National Graduate School in Nanoscience (NGS-NANO, 2007-2011) PCC - Participant in Graduate Schools

  13. Johan GadolinScholarships “Gain Expertise in Chemistry & Chemical Engineering in Finland” 2007-2011

  14. Johan GadolinScholarships • Funded by Åbo Akademi Foundation • Funding period: 2007-2009, 2010-2011 • Amount: 150.000 € per year, 750.000 € in total • Chairman: Prof. Mikko Hupa • Coordinator: Lotta Österholm • Website: http://web.abo.fi/fak/tkf/cmc/jgs/mc/

  15. Johan GadolinScholarships • Who canapply? • PhD-students and post doctoral researchers from countriesoutside Finland from and a widerange of scientificfields • Whatcanwe offer? • A research visit between 3 to 12 months in one of the laboratories of the Åbo Akademi Process Chemistry Centre

  16. Scientificscope • Biofuel combustion and functional inorganic materials, Prof. MikkoHupa • Catalysis and kinetics, reaction engineering, Academy Prof. TapioSalmi • Chemical aspects of wood, pulping and papermaking, biorefinery, Prof. BjarneHolmbom, Prof. Stefan Willför • Electroactive materials, chemical sensors, environmental and on-line analysis, Prof. Ari Ivaska

  17. Johan GadolinScholarships • Over 100 applicationsreceived so far, 32 havebeenaccepted (32%) • Distribution of Fellows: 18 PhD-students (56%), 13 Post docs (41%), 1 Professor (3%) • Researchers from 17countries and 27 different universitiesworld-widehaveparticipated in the scholarshipprogramme

  18. Publications • 56 published articles and 51 conferenceproceedings(Dec. 2010) • Publications in journals such as: • Industrial & Engineering Chemistry Research • Chemical Engineering Journal • Journal of the American Chemical Society • ElectrochimicaActa • Analytical Chemistry • Green Chemistry • Journal of Materials Research • Fuel • Energy & Fuels • Molecules • Wood Science and Technology • Holzforschung • Journal of Molecular Catalysis A • ChemCatChem

  19. Johan GadolinFellows • Nicola Gemo, PhD student, Università degli Studi di Padova, Italy • Innovation Engineering: Studying Hydrogen PeroxideDirectSynthesis • Ron Janzon, post doc, vTI-Institute of Wood Technology and Wood Biology, Germany • Developing and Testing Organic Fillers Madefrom Agricultural SideStreams • Ravi Inder Singh, post doc, Guru NanakDevEngineering College, India • CFD Analysis for Fluidized Bed CombustionBased on VariousBiomassFuels • MizhangXiao, post doc, Chinese Academy of Science, China • Preparation and Characterization of Silica-basedFunctionalGlasses and Ceramics with Nano-sizedParticles

  20. Johan GadolinFellows Johan Gadolin Fellows2011: Justyna Kupis, Adriana Ferancová Johan GadolinFellows and PCC Professors

  21. Johan GadolinFellows 2007-2009 Siswati Lestari, Australia Siim Link, Estonia Maria Peshkova, Russia Irina Simakova, Russia Ivan Sumersky, Russia Julia Szücs, Hungary Agnes Varga, Hungary Zhijuan Wang, China • Sylvia Bialczak, Poland • PierdomenicoBiasi, Italy • Betiana Campo, Argentina • Gordon Driver, Canada • EmrahDönmez, Turkey • Hongyu Guan, China • Dongxue Han, China • AybenKilic, Turkey

  22. Johan GadolinFellows 2009-2011 Rafael Hernandez, Spain Ron Janzon, Germany Anna Kisiel, Poland JustynaKupis, Poland Jonathan Massera, France Manuel Miró, Spain Ravi Inder Singh, India Ivan Sumerskiy, Russia MizhangXiao, China • ProthibanathBanerjee, India • WarunyaBoonjob, Thailand • RemediosCortese, Italy • Adriana Ferancova, Slovakia • Nicola Gemo, Italy • MarcinGuzinski, Poland • Erik Hagelbols, Netherlands

  23. Johan GadolinFellows Johan GadolinFellows 2010 WarunyaBoonjob and Rafael Hernandez

  24. Doctoral Students by Origin 2011

  25. Organization

  26. PCC Executive Board Prof. Bjarne Holmbom Prof. Mikko Hupa Prof. Ari Ivaska Academy Prof. Tapio Salmi 15 meetings 2010 Coordination: Maria Ljung Johan Gadolin Scholarships: Lotta Österholm PCC Task Forces Anders Brink Rose-Marie Latonen PäiviMäki-Arvela Anna Sundberg Markus Engblom Kim Granholm Matias Kangas Robin Manelius PCC Newsletter Andreas Bernas

  27. Annualreport Science fairs and events Anders Brink, Rose-Marie Latonen, PäiviMäki-Arvela, Anna Sundberg PCC Task Force I

  28. Workshops, internalseminars, wintercolloquiums Instrumentalmethods, Part I, October 14, 2005 Instrumentalmethods, Part II, November 18, 2005 Metalsfromwood – Biorefinery aspects, February 3, 2006 Introduction to modelling at PCC, April 25, 2006 Functionalmaterials, Part I, June 16, 2006 Functionalmaterials, Part II, November 11, 2006 Biochemistry in Åbo – an opportunity for PCC?, May 16, 2007 Young Scientists – Session I, January 25, 2008 Young Scientists – Session II, May 8, 2008 Course: ”Effective Presentation Skills in English”, February 2009 Markus Engblom, Kim Granholm, Matias Kangas, Robin Manelius PCC Task Force II

  29. Prof. TakashiKakiuchi, Kyoto University, Japan: "InterfacialChemistry of IonicLiquids", March2010 Prof. Rüdiger Lange, Technische Universität Dresden, Germany: "ProcessIntensification of Three-Phase Fixed BedReactors", March 2010 Prof. Miron Landau, Ben-Gurion University of the Negev, Beer-Sheva, Israel , “Grain Boundaries in Nanocrystals Assembled of Mesoporous Materials as an Available Source of Catalytic Active Sites”, April 2010 Prof. Galip Akay, Newcastle University, Newcastle upon Tyne, UK: "Agro-, Bio-, Chemical- and Energy Conversion - Process Intensifications and their applications in Intensified Integrated Plants and Engineered Ecosystems”, June 2010 Prof. James W. Frederick, Golden, CO, USA: "Integrated Biorefineries”, June 2010 Prof. Andrzej Stankiewicz, Delft University of Technology, the Netherlands: “Perfect Chemical Reactors: Towards Full Control of Chemical Transformations at Molecular Level”, August 2010 Distinguished Lecturers 2010 (I)

  30. Prof. Tadashi Kokubo, Chubu University, Japan: ”Preparation of NovelBioactive Ti-basedMetals by Simple Chemical and Heat Treatments”, September 2010 Prof. Adam Pron, Laboratoire d’Electronique Moléculaire Organique et Hybride, CEA Grenoble, France: “Organic and Hybrid (Organic/Inorganic) Electronics - A Chemist Approach”, October 2010 Prof. John Villadsen, Technical University of Denmark, Lyngby, Denmark: "Bio-reaction Engineering - A Multidisciplinary Research Field“, November 2010 Prof. Dage Sundholm, Department of Chemistry, University of Helsinki, Helsinki, Finland: "Magnetically Induced Current Densities in Molecules“, December 2010 Assoc. Prof. Harry Brumer, Division of Glycoscience, School of Biotechnology, Royal Institute of Technology (KTH), Stockholm, Sweden: "Polysaccharide Functionalization: XG and Beyond“, December 2010 Distinguished Lecturers 2010 (II)

  31. PCC Web http://www.abo.f/instut/pcc/

  32. Economy and Output

  33. Projects 2010 • Total number of projects: 55 • National research programmes: • Ketju / FA • FiDiPro/Tekes • Forestcluster • EU programmes: 5 • Academy of Finland: 13 • Tekes + Industry: 22 • Others: 17

  34. EU Projects 2010-2011 • Micro- and Milliscale Reactor Technology • COST Action FP0901, “Analytical Methods for Biorefineries” • Shipping-induced NOx and SOx Emissions - OPerational Monitoring Network (SNOOP) • COST Action CM901, “Detailed Chemical Kinetic Models for Cleaner Combustion” • Pressurized PEM Electrolyzer Stack (PrimoLyzer) August 26, 2011

  35. Funding 2010(Total 7.5 M €) August 26, 2011

  36. Funding 2000-2010

  37. Output 2000 - 2010

  38. Journal Articles 2000-2010

  39. PCC Co-operation, Output 2005 - 2009

  40. PCC Honours (I) • Anna Sundberg • Harry Elving Prize 2010 for outstanding teaching achievments • Pasi Virtanen • Best DoctoralThesis in the field of catalysis 2010, FinnishCatalysisSociety • Olatunde Jogunola • Award for Best Annual Report and Presentation 2010, Graduate School in Chemical Engineering (GSCE)

  41. PCC Honours (II) • A. Brink, T. Laurén, M. Hupa, R. Koschack, C. Mueller • Best Paper on RecoveryCycle, 2010 TAPPI International Chemical Recovery Conference, Williamsburg, VA, USA • N. DeMartini, P. Yrjas, M. Hupa, E. Monedero • Best Paper on Black Liquor, 2010 TAPPI International Chemical Recovery Conference, Williamsburg, VA, USA

  42. PCC Honours (III) • Juho Lehmusto • Best Conference Paper, Impacts of Fuel Quality on Power Production and the Environment, Saariselkä, Finland • J. Lehmusto, P. Yrjas, B-J. Skrifvars, M. Hupa, Effect of potassium chloride and potassium carbonate on the high temperature corrosion of pure Cr and 304L

  43. PCC Conference Organization (I) • Impacts of Fuel Quality on Power Production and the Environment • August 30-September 3, 2010, Saariselkä, Finland

  44. PCC Conference Organization (II) • 9th Spring Meeting of the International Society of Electrochemistry • May 8-11, 2011, Turku, Finland

  45. PCC Conference Organization (III) • Catalysis in MulthiphaseReactors & International Symposium on MultifunctionalReactors • May 22-25, 2011, Naantali, Finland

  46. Chemistry in Forest BiorefineriesBIORAFF II 1.1.2009 - 31.12.2011 ÅboAkademi University

  47. Chemistry in Forest Biorefineries “Replacing petroleum-based synthetic materials and energy with wood-derived materials” • Identify new products as well as separation and conversion technologies • Focus on chemistry • Value-added use of trees as raw material • Evaluate environmental effects

  48. Partners

  49. paper Kraft PulpMill pulping chemicals pulp pulping chips chipping stemwood debarking round wood black liquor bark harvesting heat power & com- bustion pulping chemicals emissions ash

  50. paper Kraft Pulp Mill & Biorefinery WP1 pulping chemicals pulp pulping chips chipping stemwood WP3 extraction knots debarking round wood black liquor WP1 WP2 extraction P WP 2 P bark P harvesting separation P WP2 P extraction residues & heat power WP4 com- bustion pyrolysis gasifica- tion WP5 pyrolysis products biofuels (l) WP5 WP5 synthesis gas pulping chemicals synthesis emissions P ash recycling

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