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Solution Conductivity. Guiding Questions. What is meant by dissociation? What is the molecular arrangement of water molecules?. A. Definitions. Solution - homogeneous mixture. Solute - substance being dissolved. Solvent - present in greater amount.
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Guiding Questions What is meant by dissociation? What is the molecular arrangement of water molecules?
A. Definitions • Solution - homogeneous mixture Solute - substance being dissolved Solvent - present in greater amount
Arrhenius’s Theory ofElectrolytic Dissociation • Why do some solutions conduct electricity? • An early hypothesis was that electricity produced ions in solution, and those ions allowed the electricity to flow. • Arrhenius’s theory: • Certain substances dissociate into cations and anions when dissolved in water. • The ions already present in solution allow electricity to flow.
Dissociation • http://www.mhhe.com/physsci/chemistry/essentialchemistry/flash/molvie1.swf
Nonpolar vs. Polar • When nonpolar substances dissolve in one another, they simply mix. • When polar substances dissolve, electrical reactions pull apart the molecules.
K+(aq) + MnO4-(aq) IONIC COMPOUNDSCompounds in Aqueous Solution Many reactions involve ionic compounds, especially reactions in water — aqueous solutions. KMnO4 in water
ELECTROLYTES • Are substances that form positive(+) and negative (-) ions in water • Conduct an electric current
Types of Electrolytes • A strong electrolyte dissociates completely. • A strong electrolyte is present in solution almost exclusively as ions. • Strong electrolyte solutions are good conductors. • A weak electrolyte dissociates partially. • Weak electrolyte solutions are poor conductors. • Different weak electrolytes dissociate to different extents. • A nonelectrolyte does not dissociate. • A nonelectrolyte is present in solution almost exclusively as molecules. • Nonelectrolyte solutions do not conduct electricity.
Electrolytic Properties of Aqueous Solutions • Electrolytesdissociate to produce ions. The more the electrolyte dissociates, the more ions it produces.
Is it a strong electrolyte, a weak electrolyte, or a nonelectrolyte? • Strong electrolytes include: • Strong acids (HCl, HBr, HI, HNO3, H2SO4, HClO4) • Strong bases (IA and IIA hydroxides) • Most water-soluble ionic compounds • Weak electrolytes include: • Weak acids and weak bases • A few ionic compounds • Nonelectrolytes include: • Most molecular compounds • Most organic compounds (most of them are molecular) How do we tell whether an acid (or base) is weak?
- + - - + + acetic acid salt sugar B. Solvation Non- Electrolyte Weak Electrolyte Strong Electrolyte solute exists as ions and molecules solute exists as ions only solute exists as molecules only DISSOCIATION IONIZATION View animation online.
Electrolytes in the Body • Carry messages to and from the brain as electrical signals • Maintain cellular function with the correct concentrations electrolytes