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This chapter explores the historical development of the periodic law, beginning with Cannizzaro's innovative method for determining atomic masses in 1860, which laid the groundwork for organizing elements. Mendeleev's 1869 periodic table highlighted the periodicity of properties and facilitated the prediction of undiscovered elements. Moseley’s 1911 use of X-rays established the modern arrangement based on atomic number. Key trends such as atomic radius, ionic radius, ion formation, ionization energy, electron affinity, and electronegativity are also discussed, illustrating the consistent patterns in element behavior.
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Chapter 5 The Periodic Law
History • Cannizzaro- 1860 • presented a new method for determining mass of elements • gave scientists a way to organize elements
History • Mendeleev-Russian 1869 • organized elements according to mass and properties • noticed that properties repeated periodically • predicted elements, later identified as Sc,Ga,Ge
History • Moseley-1911 • Used X-rays for determining the # of protons • This is how our current periodic table is arranged.
Periodic Law • Physical and chemical properties repeat periodically if arranged according to atomic number. Recurring or reappearing from time to time; intermittent. http://www.thefreedictionary.com • Look for overall patterns- may see some variation.
History • Changes since Moseley • Noble gases-Ramsay • Lanthanides/Actinides- Seaborg
The Periodic Table Trends
Atomic Radius • tells us the size of the atom • measured using ½ the distance between the nuclei of identical atoms bonded together
Atomic Radius • TREND: • going across the atoms get smaller • going down the atoms get larger
Ionic Radius • tells us the size of the ion • positive or negative atom because of loss or gain of electrons • Cation-positive ion • Anion-negative ion
Ionic Radius • Cations are smaller than the parent • Lose electrons
Ionic Radius • Anions are larger than the parent. • Gain electrons.
Ion Formation • Why do ions form? • Atoms try to become stable. • Achieve a noble gas configuration. • Become isoelectronic with noble gases • Having the same electron configuration
Ion Formation • Examples: • Calcium • Nitrogen
Ion Formation • You try these: • Potassium • Iodine • Aluminum
Ionization Energy • Amount of energy required to remove an electron from an atom
Electron Affinity • energy change when an electron is added to an atom • energy release means it is easier to add e- • opposite of ionization energy
Electronegativity • measure of the ability of an atom to attract electrons when it is bonded to another atom • Think: sharing with a partner, equal sharing or unequal sharing