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This resource aims to help students predict bond types—polar, nonpolar, and ionic—using electronegativity and periodic table placement. It will explore dispersion forces, dipole-dipole interactions, and hydrogen bonding, along with hands-on exercises. The drill focuses on identifying combinations of bonded and nonbonded electron pairs in bent structures. Key concepts include distinctions among ionic, nonpolar covalent, and polar covalent bonds, as well as various intermolecular forces. This comprehensive overview will enhance comprehension of molecular interactions and polarity.
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Objectives: • To use electronegativity and the location of elements on the periodic table to predict the type of bond (polar, nonpolar, ionic) • To describe dispersion forces, dipole-dipole interaction, and hydrogen bonding
Drill: • Give all the combinations of the number of bonded pairs and nonbonded pairs of electrons for a bent structure.
Homework • Complete Worksheet • Read lab and complete pre-lab questions
Intramolecular Forces The forces of attraction that exist between bonds within a molecule.
Dipole • Charged ends of a molecule • Represented by δ+ or δ- • Slightly positive - δ+ • Slightly negative - δ-
Nonpolar Bond • When two atoms have the same electronegativity. • No dipole is formed
Polar Bond • When the electronegativities of the atoms differ. • The greater the difference the more polar the bond • A dipole may form
Ionic Bonds • Atoms on opposite sides of the table have large differences in electronegativity. • Bonds are highly polar • ΔEN > 1.8
Nonpolar Covalent Bonds • Nonmetallic atoms of the same type have the same electronegativity • Bonds are nonpolar • ΔEN < 0.4
Polar Covalent Bonds • Atoms in between these two extremes have an uneven sharing of electrons • Slightly charged atoms • 1.8 ≥ ΔEN ≥ 0.4
Intermolecular Forces • The attraction between molecules • The stronger the intermolecular forces the more energy it takes to change phases
Types of Intermolecular Forces • Ion • Charged particle • Dipole • Polar molecule • Induced dipole • Non-polar molecule induced into having a temporary dipole
Types of Intermolecular Forces • Strengths of intermolecular forces • Ion – ion (strongest) • Ion – dipole • Dipole - dipole • Dipole – induced dipole • Induced dipole – induced dipole (weakest)
Very special intermolecular force • Hydrogen bonding • An unusually strong dipole-dipole attraction • Between molecules with a hydrogen atom attached to a very electronegative atom • (F or O or N or . . .)
Molecular Polarity • Non Polar Molecule • All bonds in the molecule are nonpolar • Dipoles of equal strength but pull in opposite directions, cancel each other out. The net result is an even distribution of bonding electrons around the whole molecules • Often symmetrical in shape
Molecular Polarity • Polar Molecule • There is an uneven distribution of bonding electrons. • Often asymmetrical in shape