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This presentation explores the atomic line assignments for the molecule CH2Br2 through Resonance Enhanced Multi-Photon Ionization (REMPI) spectroscopy. We focus on the transitions within the C(2p2) and C(2p4p) states along with observed spectral shifts. Data comparisons are made to analogous analyses in CH3Br, with detailed references provided for further investigation. The findings contribute to a deeper understanding of molecular behavior and dynamics within halogenated compounds.
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C+ atomic lines, CH2Br2: https://notendur.hi.is/~agust/rannsoknir/rempi/ch2br2/Jan14/PPT-140513.pptx https://notendur.hi.is/~agust/rannsoknir/rempi/ch2br2/Jan14/PXP-140513.pxp(<= rempi….CH2Br2/CH2Br2_18000_20350.pxp) https://notendur.hi.is/~agust/rannsoknir/rempi/ch2br2/Jan14/XLS-140513.xlsx
NIST: https://notendur.hi.is/~agust/rannsoknir/rempi/ch2br2/Jan14/XLS-140513.xlsx
C(2p2: 3PJ) C**(2p4p:3P23P13P0) Spectrumseemstobeslightlyshifted! 2hv/cm-1 https://notendur.hi.is/~agust/rannsoknir/rempi/ch2br2/Jan14/PXP-140513.pxp
Seeanalogous analysis (for CH3Br; lowerenergy ) inhttp://www3.hi.is/~agust/rannsoknir/rempi/ch3br/Jan10/PPT-150110ak.ppt Other C atomiclineassignments (for CH3Br): http://www3.hi.is/~agust/rannsoknir/rempi/ch3br/Sept09/PPT-231009ak.ppt http://www3.hi.is/~agust/rannsoknir/rempi/ch3br/Sept09/PPT-271009ak.ppt